Bifunctional BiPd Alloy Particles Anchored on Carbon Matrix for Reversible Zn–CO2 Battery
Source abstract
Abstract
Exploring reversible Zn–CO2 batteries holds great promising potential for future CO2 fixation and energy supply. Herein, the bifunctional PdBi alloy anchoring on carbon substrate (BiPdC) is proposed for simultaneously catalyzing carbon dioxide reduction reaction (CO2RR) and formic acid oxidation (FAO). The synergistic effect between Pd and Bi overcomes the sluggish kinetics of CO2RR and FAO, causing the HCOOH Faraday efficiency (FEHCOOH) of 63.4% and 6.2 mA cm–2 current density for FAO. Benefiting from the CO2–HCOOH interconversion, the homemade reversible Zn–CO2 battery exhibits the optimal 52.6% FEHCOOH and 1.1 V voltage gap within 45 h of cycling.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: CO2 Reduction Techniques and Catalysts · Advanced battery technologies research · Carbon dioxide utilization in catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute for New Energy Materials and Low-Carbon Technologies, Tianjin Key Lab for Photoelectric Materials & Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
Institute for Advanced Study, Chengdu University, Chengdu 610106, Sichuan, China
College of Chemistry, Zhengzhou University, Zhengzhou 450000, China
Tianjin Key Lab for Photoelectric Materials & Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
MOE Key Laboratory of New Processing Technology for Non-Ferrous Metals and Materials, and Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, School of Resource, Environments and Materials, Guangxi University, Nanning 530004, China
Funding
Natural Science Foundation of Tianjin City · National Natural Science Foundation of China
References (79)
Show source-provided references
1. 10.1002/adma.20190379010.1002/adma.201903790 ↗
2. 10.1002/adma.20160589110.1002/adma.201605891 ↗
3. 10.26599/NRE.2022.912001510.26599/NRE.2022.9120015 ↗
4. 10.1016/j.apcatb.2018.08.08110.1016/j.apcatb.2018.08.081 ↗
5. 10.1002/adfm.20190828510.1002/adfm.201908285 ↗
6. 10.1002/smll.20190582510.1002/smll.201905825 ↗
7. 10.1021/jacs.9b1211110.1021/jacs.9b12111 ↗
8. 10.1016/j.ccr.2020.21343510.1016/j.ccr.2020.213435 ↗
9. 10.1021/acsaem.8b0074410.1021/acsaem.8b00744 ↗
10. 10.1039/C8TA04758H10.1039/C8TA04758H ↗
11. 10.1002/smll.20190222910.1002/smll.201902229 ↗
12. 10.1016/j.inoche.2021.10858710.1016/j.inoche.2021.108587 ↗
13. 10.1007/s40843-021-1890-710.1007/s40843-021-1890-7 ↗
14. 10.1021/acs.nanolett.1c0111310.1021/acs.nanolett.1c01113 ↗
15. 10.26599/NRE.2022.912002110.26599/NRE.2022.9120021 ↗
16. 10.1002/smll.20210496510.1002/smll.202104965 ↗
17. 10.1016/j.apcatb.2022.12114510.1016/j.apcatb.2022.121145 ↗
18. 10.1016/j.cej.2022.13529410.1016/j.cej.2022.135294 ↗
19. 10.1039/D0EE02833A10.1039/D0EE02833A ↗
20. 10.1002/anie.20220059810.1002/anie.202200598 ↗
21. 10.26599/NRE.2022.912002210.26599/NRE.2022.9120022 ↗
22. 10.26599/NRE.2022.912001010.26599/NRE.2022.9120010 ↗
23. 10.1039/D2CC02463B10.1039/D2CC02463B ↗
24. 10.1002/adma.20160468510.1002/adma.201604685 ↗
25. 10.1039/D1SC07212A10.1039/D1SC07212A ↗
26. 10.1002/anie.20181185310.1002/anie.201811853 ↗
27. 10.1039/D1GC02496E10.1039/D1GC02496E ↗
28. 10.1016/j.nanoen.2021.10678010.1016/j.nanoen.2021.106780 ↗
29. 10.1002/adfm.20190896510.1002/adfm.201908965 ↗
30. 10.1002/cnma.20200009910.1002/cnma.202000099 ↗
31. 10.1039/D1TA04360A10.1039/D1TA04360A ↗
32. 10.1021/acsami.0c1344010.1021/acsami.0c13440 ↗
33. 10.1039/D0TA03050C10.1039/D0TA03050C ↗
34. 10.1016/j.cclet.2021.10.06310.1016/j.cclet.2021.10.063 ↗
35. 10.1002/smll.20220131110.1002/smll.202201311 ↗
36. 10.1002/advs.20190298910.1002/advs.201902989 ↗
37. 10.1007/s12274-017-1514-610.1007/s12274-017-1514-6 ↗
38. 10.1016/j.apsusc.2020.14555410.1016/j.apsusc.2020.145554 ↗
39. 10.1021/acscatal.5b0060210.1021/acscatal.5b00602 ↗
40. 10.1021/acscatal.6b0323710.1021/acscatal.6b03237 ↗
41. 10.1039/D2CC00114D10.1039/D2CC00114D ↗
42. 10.1016/j.jpowsour.2017.04.07010.1016/j.jpowsour.2017.04.070 ↗
43. 10.1016/S1872-2067(21)63999-210.1016/S1872-2067(21)63999-2 ↗
44. 10.1016/j.ijhydene.2019.05.22310.1016/j.ijhydene.2019.05.223 ↗
45. 10.1002/adfm.20210346510.1002/adfm.202103465 ↗
46. 10.1016/j.ijhydene.2022.02.23510.1016/j.ijhydene.2022.02.235 ↗
47. 10.1039/D1SC06314F10.1039/D1SC06314F ↗
48. 10.1021/acsaem.1c0370310.1021/acsaem.1c03703 ↗
49. 10.1039/C8TA10958C10.1039/C8TA10958C ↗
50. 10.1166/jnn.2019.1658910.1166/jnn.2019.16589 ↗
51. 10.1002/anie.20180757110.1002/anie.201807571 ↗
52. 10.1002/adma.20180780710.1002/adma.201807807 ↗
53. 10.1039/D1TA07522E10.1039/D1TA07522E ↗
54. 10.1007/s11581-022-04634-z10.1007/s11581-022-04634-z ↗
55. 10.1039/D2QI00083K10.1039/D2QI00083K ↗
56. 10.1007/s12274-022-4208-710.1007/s12274-022-4208-7 ↗
57. 10.1126/sciadv.abm377910.1126/sciadv.abm3779 ↗
58. 10.1007/s40843-021-1902-210.1007/s40843-021-1902-2 ↗
59. 10.1007/s12274-020-3186-x10.1007/s12274-020-3186-x ↗
60. 10.1002/adfm.20200393310.1002/adfm.202003933 ↗
61. 10.1021/acs.accounts.9b0017910.1021/acs.accounts.9b00179 ↗
62. 10.1002/smtd.20200103910.1002/smtd.202001039 ↗
63. 10.1002/adma.20200243010.1002/adma.202002430 ↗
64. 10.1002/adfm.20190765810.1002/adfm.201907658 ↗
65. 10.26599/NRE.2022.912000110.26599/NRE.2022.9120001 ↗
66. 10.1039/D2CC01888H10.1039/D2CC01888H ↗
67. 10.26599/NRE.2022.912001210.26599/NRE.2022.9120012 ↗
68. 10.26599/NRE.2022.912000610.26599/NRE.2022.9120006 ↗
69. 10.26599/NRE.2022.912000810.26599/NRE.2022.9120008 ↗
70. 10.1039/D2CC02463B10.1039/D2CC02463B ↗
71. 10.26599/NRE.2022.912000310.26599/NRE.2022.9120003 ↗
72. 10.1016/j.jallcom.2022.16611310.1016/j.jallcom.2022.166113 ↗
73. 10.1007/s12598-020-01415-310.1007/s12598-020-01415-3 ↗
74. 10.1063/5.009747910.1063/5.0097479 ↗
75. 10.3866/PKU.WHXB20200903310.3866/PKU.WHXB202009033 ↗
76. 10.3866/PKU.WHXB20200904310.3866/PKU.WHXB202009043 ↗
77. 10.1007/s12274-022-4747-y10.1007/s12274-022-4747-y ↗
78. 10.1007/s12598-019-01203-810.1007/s12598-019-01203-8 ↗
79. 10.14102/j.cnki.0254-5861.2011-274410.14102/j.cnki.0254-5861.2011-2744 ↗