journal article·2018-12-28

Graphene Oxide/Iron Oxide Nanocomposites for Water Remediation

Stefania Mura, Yu Jiang, Irene Vassalini, Alessandra Gianoncelli, Ivano Alessandri, Gaetano Granozzi, Laura Calvillo, Nina Senes, Stefano Enzo, Plinio Innocenzi, Luca Malfatti

ACS Applied Nano Materials· Volume 1· Issue 12
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Abstract

Graphene oxide/iron (III–VI) oxides nanocomposites have been produced with a fast and one-pot synthesis. K2FeO4 (Fe(VI)-based compound), obtained from a dry synthesis, has been used as a green oxidant of graphite to produce graphene oxide, avoiding the use of the toxic permanganates. Graphene oxide flakes with a low oxidation degree and decorated with iron oxide have been obtained in one-step reaction. The material has been characterized by several techniques to investigate the structure (SEM, TEM analysis), the composition (X-ray fluorescence, XPS, FTIR, UV–visible, fluorescence, and Raman spectroscopy) and the performance (HPLC). The combined use of ferrate and graphene oxide/iron oxide is an efficient, cheap, and green alternative for water remediation. Real water samples containing different types of emerging pollutants (organic dyes, pesticides, and pharmaceutical drugs) have been efficiently decontaminated obtaining an abatement of 99% in a few minutes. The nanocomposite is paramagnetic and can be easily removed from water with a magnet after depollution. The materials have shown one of the best decontamination performance reported in the scientific literature so far.
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Research context

OpenAlex topics: Graphene and Nanomaterials Applications · Environmental remediation with nanomaterials · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratorio di Scienza dei Materiali e Nanotecnologie, CR-INSTM, Dipartimento di Chimica e Farmacia, Università di Sassari, CR-INSTM, Via Vienna 2, 07100 Sassari, Italy

INSTM-UdR Brescia, Via Branze 38, 2513 Brescia, Italy

Chemistry for Technologies Laboratory, Dipartimento di Ingegneria Meccanica e Industriale, Università di Brescia, Via Branze 38, 25123 Brescia, Italy

Dipartimento di Medicina Molecolare e Traslazionale, Università degli Studi di Brescia, Viale Europa 11, 25123 Brescia, Italy

Dipartimento di Ingegneria dell’Informazione, Università di Brescia, Via Branze 38, 25123 Brescia, Italy

Dipartimento di Scienze Chimiche, Università di Padova, Via Marzolo 1, 35131 Padova, Italy

Dipartimento di Chimica e Farmacia, Università di Sassari, CR-INSTM, Via Vienna 2, 07100 Sassari, Italy

Funding

Ministero degli Affari Esteri e della Cooperazione Internazionale · Regione Lombardia · Regione Autonoma della Sardegna

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