journal article·2024-03-08Open access

Sulfur-Enriched Nanoporous Carbon: A Novel Approach to CO2 Adsorption

Chen Liu, Yue Zhi, Qiyun Yu, Lifeng Tian, Muslum Demir, Suleyman Gokhan Colak, Ahmed A. Farghaly, Linlin Wang, Xin Hu

ACS Applied Nano Materials· Volume 7· Issue 5

Abstract

Carbon dioxide (CO 2 ) intake plays a vital role in sustaining the environmental balance by influencing global carbon dynamics and climatic stability. This work addresses the production of sulfur-doped porous nanocarbons (SDCs) as prospective sorbents for CO 2 capture. SDCs were fabricated by utilizing coconut shell as a carbon precursor and potassium persulfate as both a chemical activating agent and a sulfur dopant. The incorporation of sulfur functionalities into carbon matrices creates structural variability and active sites, boosting CO 2 absorption capabilities. Sulfur’s peculiar electrical structure allows greater intermolecular interactions with CO 2, enhancing adsorption affinities. According to the experimental data, the CO 2 uptake was best measured as 3.37 mmol/g at 0 °C and 1 bar and 2.56 mmol/g at 25 °C and 1 bar. The results show that the higher porosity of SDC materials adds to a large amplification in the CO 2 uptake capability. The work underlines the delicate interaction between sulfur doping, morphological porosity, and surface reactivity in enhancing the effectiveness of CO 2 sequestration. SDC materials hold considerable promise in tackling the present ecological concerns and developing CO 2 collection techniques. The suggested single-step synthesis technique described here provides a sustainable and environmentally friendly method for synthesizing SDCs for carbon capture applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Carbon Dioxide Capture Technologies · Covalent Organic Framework Applications · Membrane Separation and Gas Transport

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua, Zhejiang 321004, P.R. China

Department of Chemical Engineering, Bogazici University, Istanbul 34342, Turkey

TUBITAK Marmara Research Center, Material Institute, Gebze 41470, Turkey

Department of Biomedical Engineering, Faculty of Engineering and Natural Sciences, Iskenderun Technical University, Hatay 31200, Turkey

Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States

Pritzker School of Molecular Engineering, The University of Chicago, Chicago, Illinois 60637, United States

Chemistry Department, Faculty of Science, Assiut University, Assiut 71516, Egypt

Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology and Equipment of Zhejiang Province, College of Engineering, Zhejiang Normal University, Jinhua, Zhejiang 321004, PR China

Funding

National College Students Innovation and Entrepreneurship Training Program · Zhejiang Normal University · Natural Science Foundation of Zhejiang Province

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