Raman spectroscopic study of the rare-earth fullerides Eu6−xSrxC60

We present Raman spectroscopic studies of the isostructural and isoelectronic Eu(6-x)Sr(x)C(60) (x = 0, 3, 5, 6) and Ba(6)C(60) compounds. The Raman spectra of the Eu-based fullerides show dramatic changes compared to the pure alkaline-earth systems, including significant broadening, splitting and frequency shifts of the fivefold degenerate H(g) intramolecular modes of C(60). Moreover, the A(g)(2) mode exhibits an even larger downshift and a remarkable broadening. These findings are consistent with distortions of the C(60) molecular cages and a considerable electron-phonon coupling strength-strongly enhanced in the Eu containing systems-originating from the strong orbital hybridization between the metal atom and the C(60) molecule.