journal article·2024Open access

Unraveling a volcanic relationship of Co/N/C@Pt x Co catalysts toward oxygen electro-reduction

Yangdong Zhou, Junda Chen, Zhiyin Huang, Yuqin Peng, Lixin Xing, Chunmei Tang, Ning Wang, Ling Meng, Mingjie Wu, Lei Du, Siyu Ye

Nanoscale· Volume 16· Issue 10

Abstract

Co catalysts are synthesized. Interestingly, the ORR activity and stability are not linear with the Pt content, but show a volcano-like curve with increased Pt usage. This relationship has been deeply unraveled to be closely related to the contents of pyrrolic N, pyridinic N, and graphitized carbon in catalysts. This work provides guidelines to rationally design the coupled PGM-free@PGM catalysts toward the ORR by appropriate surface engineering.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advanced Memory and Neural Computing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Huangpu Hydrogen Energy Innovation Centre/School of Chemistry and Chemical Engineering, Guangzhou University, Wai Huan Xi Road 230, Guangzhou 510006, P. R. China

State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan 430200, P. R. China

SinoHykey Technology Company Ltd., 8 Hongyuan Road, Huangpu District, Guangzhou 510760, P. R. China

Funding

Natural Science Foundation of Guangdong Province · Guangzhou Municipal Science and Technology Project · National Natural Science Foundation of China

References (59)

Show source-provided references
1. Zhou · Chem Catal. · 2023 · 3 · 10048410.1016/j.checat.2022.12.001 ↗
2. Du · Nano Energy · 2016 · 29 · 31410.1016/j.nanoen.2016.03.016 ↗
3. Du · Small Methods · 2020 · 4 · 200001610.1002/smtd.202000016 ↗
4. Zou · Nanoscale · 2019 · 11 · 2011510.1039/C9NR06698E ↗
5. S.Katayama , Characterization and analysis of the new generation Mirai catalysts (in Japanese), https://fc-cubic-event.jp/wp-sympo/wp-content/uploads/2022/05/bb54e72f169dae5e5c564288d6405f16.pdf
6. Zeng · Nat. Commun. · 2022 · 13 · 765410.1038/s41467-022-35457-1 ↗
7. Tian · Science · 2019 · 366 · 85010.1126/science.aaw7493 ↗
8. Owejan · J. Electrochem. Soc. · 2013 · 160 · F82410.1149/2.072308jes ↗
9. Kongkanand · J. Phys. Chem. Lett. · 2016 · 7 · 112710.1021/acs.jpclett.6b00216 ↗
10. Prabhakaran · J. Electrochem. Soc. · 2016 · 163 · F161110.1149/2.1311614jes ↗
11. Huang · Front. Energy · 2017 · 11 · 33410.1007/s11708-017-0490-6 ↗
12. Shen · Phys. Chem. Chem. Phys. · 2017 · 19 · 2622110.1039/C7CP04837H ↗
13. Ahluwalia · J. Electrochem. Soc. · 2018 · 165 · F331610.1149/2.0341806jes ↗
14. Singh · J. Electrochem. Soc. · 2018 · 165 · F332810.1149/2.0351806jes ↗
15. Cheng · J. Electrochem. Soc. · 2019 · 166 · F105510.1149/2.0501914jes ↗
16. Pan · Curr. Opin. Electrochem. · 2019 · 18 · 6110.1016/j.coelec.2019.10.011 ↗
17. Schuler · J. Electrochem. Soc. · 2019 · 166 · F302010.1149/2.0031907jes ↗
18. Wang · J. Electrochem. Soc. · 2019 · 166 · F23910.1149/2.0401904jes ↗
19. Zheng · Electrochim. Acta · 2019 · 323 · 13475110.1016/j.electacta.2019.134751 ↗
20. Borup · Curr. Opin. Electrochem. · 2020 · 21 · 19210.1016/j.coelec.2020.02.007 ↗
21. Ott · Nat. Mater. · 2020 · 19 · 7710.1038/s41563-019-0487-0 ↗
22. Zheng · J. Power Sources · 2020 · 451 · 22772910.1016/j.jpowsour.2020.227729 ↗
23. Cheng · Int. J. Heat Mass Transfer · 2021 · 164 · 12054910.1016/j.ijheatmasstransfer.2020.120549 ↗
24. Du · Adv. Mater. · 2021 · 33 · e190823210.1002/adma.201908232 ↗
25. Yang · J. Mater. Sci. Technol. · 2024 · 173 · 10010.1016/j.jmst.2023.08.004 ↗
26. Zhou · Small · 2023 · 19 · 230232810.1002/smll.202302328 ↗
27. Lai · Nano Lett. · 2021 · 21 · 797010.1021/acs.nanolett.1c02013 ↗
28. Yin · ACS Nano · 2023 · 18 · 55110.1021/acsnano.3c08570 ↗
29. Chen · Small · 2023 · 19 · e230133710.1002/smll.202301337 ↗
30. Guo · Energy Environ. Sci. · 2023 · 16 · 14810.1039/D2EE02381D ↗
31. Zeng · ACS Catal. · 2023 · 13 · 1187110.1021/acscatal.3c03270 ↗
32. Xiao · Nat. Catal. · 2022 · 5 · 50310.1038/s41929-022-00796-1 ↗
33. Xiong · ACS Nano · 2020 · 14 · 1306910.1021/acsnano.0c04559 ↗
34. Huang · Angew. Chem., Int. Ed. · 2021 · 60 · 2553010.1002/anie.202111426 ↗
35. Guo · ACS Appl. Mater. Interfaces · 2022 · 14 · 5381910.1021/acsami.2c15996 ↗
36. Chong · Science · 2018 · 362 · 127610.1126/science.aau0630 ↗
37. Chong · Chem Catal. · 2023 · 3 · 10054110.1016/j.checat.2023.100541 ↗
38. Liu · Argonne National Laboratory · 2020
39. Luo · Adv. Mater. · 2023 · 35 · 230062410.1002/adma.202300624 ↗
40. Sun · ACS Appl. Mater. Interfaces · 2019 · 11 · 4125810.1021/acsami.9b11830 ↗
41. Sun · J. Power Sources · 2023 · 562 · 23275810.1016/j.jpowsour.2023.232758 ↗
42. Wang · Prog. Nat. Sci. · 2020 · 30 · 85510.1016/j.pnsc.2020.09.010 ↗
43. Shang · Adv. Mater. · 2015 · 28 · 166810.1002/adma.201505045 ↗
44. Ye · Nano Energy · 2017 · 38 · 28110.1016/j.nanoen.2017.05.042 ↗
45. Chi · ACS Catal. · 2023 · 13 · 422110.1021/acscatal.2c06118 ↗
46. Greeley · Nat. Chem. · 2009 · 1 · 55210.1038/nchem.367 ↗
47. Kitchin · J. Chem. Phys. · 2004 · 120 · 1024010.1063/1.1737365 ↗
48. Lai · ACS Catal. · 2023 · 13 · 1199610.1021/acscatal.3c02152 ↗
49. Yu · Adv. Energy Mater. · 2022 · 12 · 220011010.1002/aenm.202200110 ↗
50. Wang · Nano Lett. · 2018 · 18 · 416310.1021/acs.nanolett.8b00978 ↗
51. Li · Fuel · 2023 · 345 · 12819910.1016/j.fuel.2023.128199 ↗
52. Chen · J. Am. Chem. Soc. · 2022 · 144 · 1450510.1021/jacs.2c01194 ↗
53. Zhang · Energy Environ. Sci. · 2020 · 13 · 11110.1039/C9EE03027A ↗
54. Yan · Carbon Energy · 2021 · 3 · 85610.1002/cey2.135 ↗
55. Sun · Angew. Chem., Int. Ed. · 2023 · 62 · e20221604110.1002/anie.202216041 ↗
56. Yuan · Adv. Mater. · 2023 · 35 · 230594510.1002/adma.202305945 ↗
57. Hu · J. Am. Chem. Soc. · 2022 · 144 · 1814410.1021/jacs.2c08743 ↗
58. Qiao · Energy Environ. Sci. · 2021 · 14 · 494810.1039/D1EE01675J ↗
59. Ha · Adv. Energy Mater. · 2020 · 10 · 200259210.1002/aenm.202002592 ↗