journal article·2023

Ice crystal sublimation for easily producing MnO 2 cathodes with hierarchically porous structure and enhanced cyclic reversibility

Xiangru Si, Ruijie Zhu, Yang Yang, Huijun Yang, Nan Sheng, Chunyu Zhu

Nanoscale· Volume 15· Issue 44
Publisher page

Abstract

The charge/discharge performance of rechargeable aqueous zinc ion batteries (RAZIBs) at high currents is often unsatisfactory due to the cathode preparation process and the use of hydrophobic binders. By adding freeze-drying treatment to the preparation process of the cathodes, MnO2 cathodes with hierarchically porous structures are obtained, which provide additional channels for ion transfer, thus greatly enhancing the charge/discharge performance in aqueous Zn-MnO2 batteries.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced battery technologies research · Advancements in Battery Materials · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Low-Carbon Energy and Power Engineering, China University of Mining and Technology, Xuzhou 221116, China

Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan

National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1, Umezono, Tsukuba 305-8568, Japan

Funding

National Natural Science Foundation of China · Fundamental Research Funds for the Central Universities · Natural Science Foundation of Jiangsu Province

References (33)

Show source-provided references
1. Song · Adv. Funct. Mater. · 2018 · 28 · 180256410.1002/adfm.201802564 ↗
2. Beck · Electrochim. Acta · 2000 · 45 · 246710.1016/S0013-4686(00)00344-3 ↗
3. Yang · Energy Environ. Sci. · 2023 · 16 · 235810.1039/D3EE00501A ↗
4. Guo · Electrochim. Acta · 2019 · 304 · 37010.1016/j.electacta.2019.03.008 ↗
5. Chamoun · Energy Storage Mater. · 2018 · 15 · 35110.1016/j.ensm.2018.06.019 ↗
6. Xue · J. Energy Chem. · 2021 · 54 · 19410.1016/j.jechem.2020.05.056 ↗
7. Seo · J. Phys. Chem. C · 2018 · 122 · 1117710.1021/acs.jpcc.7b11685 ↗
8. Liu · Nanotechnology · 2020 · 31 · 12200110.1088/1361-6528/ab5b38 ↗
9. Liu · Chem. Soc. Rev. · 2020 · 49 · 18010.1039/C9CS00131J ↗
10. Lai · J. Mater. Chem. A · 2023 · 11 · 1521110.1039/D3TA02202A ↗
11. Ni · Adv. Mater. · 2020 · 32 · e200028810.1002/adma.202000288 ↗
12. Yong · Adv. Energy Mater. · 2020 · 10 · 200235410.1002/aenm.202002354 ↗
13. Zhu · Energy Storage Mater. · 2022 · 46 · 22310.1016/j.ensm.2022.01.016 ↗
14. Li · Chem. Eng. J. · 2023 · 465 · 14289710.1016/j.cej.2023.142897 ↗
15. Bi · Mater. Today Energy · 2020 · 18 · 10054810.1016/j.mtener.2020.100548 ↗
16. Jaikrajang · ACS Appl. Energy Mater. · 2021 · 4 · 713810.1021/acsaem.1c01214 ↗
17. Dong · Adv. Sci. · 2023 · 10 · e220508410.1002/advs.202205084 ↗
18. Nivedha · Catal. Today · 2021 · 370 · 6610.1016/j.cattod.2020.09.022 ↗
19. Yin · Nanoscale · 2019 · 11 · 1972310.1039/C9NR07458A ↗
20. Fan · ACS Appl. Mater. Interfaces · 2021 · 13 · 4160910.1021/acsami.1c10510 ↗
21. Ding · ACS Appl. Mater. Interfaces · 2019 · 11 · 4410910.1021/acsami.9b13729 ↗
22. Ruan · Adv. Mater. · 2023 · 35 · e230057710.1002/adma.202300577 ↗
23. Huang · J. Mater. Chem. A · 2019 · 7 · 2142110.1039/C9TA07269A ↗
24. Han · Adv. Funct. Mater. · 2021 · 32 · 210866910.1002/adfm.202108669 ↗
25. Delattre · J. Electrochem. Soc. · 2018 · 165 · A38810.1149/2.1321802jes ↗
26. Yang · Angew. Chem., Int. Ed. · 2020 · 59 · 937710.1002/anie.202001844 ↗
27. Yangs · Energy Environ. Sci. · 2023 · 16 · 213310.1039/D2EE03777G ↗
28. Zhu · J. Mater. Chem. A · 2022 · 10 · 312210.1039/D1TA10079C ↗
29. Li · Chem. Mater. · 2019 · 31 · 203610.1021/acs.chemmater.8b05093 ↗
30. Guo · Mater. Today Energy · 2020 · 16 · 10039610.1016/j.mtener.2020.100396 ↗
31. Wang · J. Phys. Chem. C · 2007 · 111 · 1492510.1021/jp074464w ↗
32. Shen · J. Electrochem. Soc. · 2013 · 160 · A184210.1149/2.084310jes ↗
33. Wang · J. Electrochem. Soc. · 2001 · 148 · A73710.1149/1.1377897 ↗