Versatile porous graphene flakes derived from alkali metal carbonates using an ultrafast and sulfuric acid-free solid-state oxidation reaction

Herein, we report on an unprecedented synthetic method for single-layered GO that takes just a few tens of minutes. This rationally designed solid-state oxidation based on alkali metal carbonates (Li2CO3, Na2CO3, K2CO3) involves a molten salt reaction, which enables the effective exfoliation and oxidation of graphene layers without using H2SO4 and KMnO4. The advantage of this approach is not only the ability to avoid the introduction of strong acid reactants in the reaction process, but this approach also leads to a 4.2 times larger specific surface area than conventional GO. For these reasons, we anticipate that this green, safe, fast and effective approach enables practical applications in graphene-based energy storage and light-absorbing black materials.