The synthesis and structure of the [PdAu 13 (PPh 3 ) 3 (SR) 7 ] + nanocluster
Source abstract
Abstract
Metal alloy nanoclusters have attracted increasing attention due to the synergistic effect of the foreign atoms. For the first time the synthesis and crystal structure of the [PdAu13(PPh3)3(SR)7]+ nanocluster is reported. The crystal structure of the nanocluster was determined by single crystal X-ray diffraction. The [PdAu13(PPh3)3(SR)7]+ nanocluster has a concave polyhedron Au9Pd kernel, which looks like a girl dancing ballet. The structure shows that [PdAu13(PPh3)3(SR)7]+ has an open shell. Meanwhile, we also carried out ultraviolet-visible (Uv-vis) absorption spectroscopy and fluorescence spectroscopy to study the optical properties of the [PdAu13(PPh3)3(SR)7]+ nanocluster.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanocluster Synthesis and Applications · Pharmacological Effects and Toxicity Studies · Amino Acid Enzymes and Metabolism
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Gold Catalysis Research Center
State Key Laboratory of Catalysis
Dalian Institute of Chemical Physics
Chinese Academy of Sciences
Dalian 116023
Laboratory of High-Resolution Mass Spectrometry Technologies
China
Funding
National Natural Science Foundation of China
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