journal article·2022Open access

Influence of Ti IV substitution on the properties of a Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 nanofiber-based solid electrolyte

Andrea La Monaca, Gabriel Girard, Sylvio Savoie, René Veillette, Sergey Krachkovskiy, Filippo Pierini, Ashok Vijh, Federico Rosei, Andrea Paolella

Nanoscale· Volume 14· Issue 13

Abstract

(LAGP) nanofibers prepared by electrospinning. Replacing a small amount of Ge (up to 20%) with Ti is advantageous for enhancing both the purity and morphology of LAGP fibers, as observed by X-ray diffraction, electron microscopy and nuclear magnetic resonance spectroscopy. When Ti-substituted LAGP (LAGTP) fibers are used as filler to develop composite polymer electrolytes, the ionic conductivity at 20 °C improves by a factor of 1.5 compared to the plain polymer electrolyte. Additionally, above 40 °C the LAGTP fiber-based composite electrolytes were more conductive than the equivalent LAGP fiber-based one. We believe that these findings can make a substantial contribution to optimizing current methods and developing novel synthesis approaches for NASICON based electrolytes.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centre d'excellence en électrification des transports et stockage d’énergie, Hydro-Québec, 1806 Boulevard Lionel-Boulet, Varennes, Québec J3X 1S1, Canada

Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Québec J3X 1P7, Canada

Institut de Recherche d'Hydro-Québec, 1800 Boulevard Lionel-Boulet, Varennes, Québec J3X 1S1, Canada

Department of Biosystems and Soft Matter, Institute of Fundamental Technological Research Polish Academy of Sciences, 02-106 Warsaw, Poland

Funding

Natural Sciences and Engineering Research Council of Canada · Canada Research Coordinating Committee

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