Enhanced CO 2 affinity in a metal–organic framework through green incorporation of a dual-functional amino acid
Source abstract
Abstract
Post-synthetic incorporation of amino acids into the Zr-based metal-organic framework DUT-67 via relatively green methods yields materials with enhanced CO2 affinity. Structural and sorption studies reveal high affinity for DUT-67-Trp, exploiting its dual functionality to achieve an adsorption enthalpy level comparable to those of high-performing frameworks. The findings provide a promising pathway towards developing sustainable amino-functionalized CO2 sorbents.
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Carbon dioxide utilization in catalysis · Carbon Dioxide Capture Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Departamento de Química Inorgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049 Madrid, Spain
Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049 Madrid, Spain
Departamento de Química inorgánica, Universidad de Granada, 18071 Granada, Spain
Funding
Agencia Estatal de Investigación · H2020 Excellent Science
References (38)
Show source-provided references
1. Climate Change 2022 – Mitigation of Climate Change: Working Group III Contribution to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change , ed. Intergovernmental Panel on Climate Change , Cambridge University Press , Cambridge , 2023 , pp. 51–148 , 10.1017/9781009157926.00210.1017/9781009157926.002 ↗
2. Boot-Handford · Energy Environ. Sci. · 2014 · 7 · 13010.1039/C3EE42350F ↗
3. Rochelle · Science · 2009 · 325 · 165210.1126/science.1176731 ↗
4. Boer · ACS Appl. Energy Mater. · 2023 · 6 · 263410.1021/acsaem.2c03605 ↗
5. Zhao · Appl. Energy · 2010 · 87 · 290710.1016/j.apenergy.2009.06.008 ↗
6. Li · Chem. Soc. Rev. · 2023 · 52 · 629410.1039/D2CS00465H ↗
7. Lyu · J. Am. Chem. Soc. · 2022 · 144 · 1298910.1021/jacs.2c05382 ↗
8. Mahajan · J. Environ. Chem. Eng. · 2022 · 10 · 10893010.1016/j.jece.2022.108930 ↗
9. Sumida · Chem. Rev. · 2012 · 112 · 72410.1021/cr2003272 ↗
10. Said · ACS Omega · 2020 · 5 · 2612510.1021/acsomega.0c03727 ↗
11. Chen · J. Am. Chem. Soc. · 2024 · 146 · 283510.1021/jacs.3c14125 ↗
12. Kim · Science · 2020 · 369 · 39210.1126/science.abb3976 ↗
13. McDonald · Nature · 2015 · 519 · 30310.1038/nature14327 ↗
14. Rubio-Gaspar · Angew. Chem., Int. Ed. · 2024 · 63 · e20240297310.1002/anie.202402973 ↗
15. Bose · Adv. Funct. Mater. · 2023 · 34 · 230747810.1002/adfm.202307478 ↗
16. Lyu · J. Am. Chem. Soc. · 2022 · 144 · 238710.1021/jacs.1c13368 ↗
17. Rao · Environ. Sci. Technol. · 2002 · 36 · 446710.1021/es0158861 ↗
18. Marino · ACS Sustainable Chem. Eng. · 2021 · 9 · 1635610.1021/acssuschemeng.1c06032 ↗
19. Bon · J. Mater. Chem. A · 2019 · 7 · 1268110.1039/C9TA00825J ↗
20. Loukopoulos · Adv. Funct. Mater. · 2024 · 34 · 240993210.1002/adfm.202409932 ↗
21. Bon · Cryst. Growth Des. · 2013 · 13 · 123110.1021/cg301691d ↗
22. Drache · Inorg. Chem. · 2016 · 55 · 720610.1021/acs.inorgchem.6b00829 ↗
23. Capello · Green Chem. · 2007 · 9 · 92710.1039/b617536h ↗
24. Nguyen · Inorg. Chem. · 2018 · 57 · 148310.1021/acs.inorgchem.7b02854 ↗
25. Romero-Muñiz · Chem. Soc. Rev. · 2024 · 53 · 1177210.1039/D4CS00267A ↗
26. Yadav · J. Mol. Struct. · 2018 · 1171 · 86710.1016/j.molstruc.2018.05.105 ↗
27. Moreno · ChemCatChem · 2024 · 16 · e20240067610.1002/cctc.202400676 ↗
28. Platero-Prats · J. Am. Chem. Soc. · 2016 · 138 · 417810.1021/jacs.6b00069 ↗
29. Xiong · Adv. Sci. · 2024 · 11 · 230812310.1002/advs.202308123 ↗
30. Demessence · J. Am. Chem. Soc. · 2009 · 131 · 878410.1021/ja903411w ↗
31. Min Wang · Microporous Mesoporous Mater. · 2002 · 55 · 21710.1016/S1387-1811(02)00405-5 ↗
32. Mason · Energy Environ. Sci. · 2011 · 4 · 303010.1039/c1ee01720a ↗
33. Shekhah · Nat. Commun. · 2014 · 5 · 422810.1038/ncomms5228 ↗
34. Si · Energy Environ. Sci. · 2011 · 4 · 452210.1039/c1ee01380g ↗
35. Lin · RSC Adv. · 2012 · 2 · 641710.1039/c2ra20641b ↗
36. Liao · Chem. Sci. · 2016 · 7 · 652810.1039/C6SC00836D ↗
37. Cabello · CrystEngComm · 2015 · 17 · 43010.1039/C4CE01265H ↗
38. Chang · J. Mater. Chem. A · 2016 · 4 · 251710.1039/C5TA08705H ↗