Recyclable luminescent metal–organic frameworks with self-formed diketone-like sites for cascade ratiometric detection
Source abstract
Abstract
@Cd-TCAT complex further acts as a cascade sensor, exhibiting ratiometric selectivity toward cysteine (Cys) over 20 natural amino acids through reversible host-guest interactions, which simultaneously regenerates the pristine MOF. Remarkably, this dual-functional platform maintains sensing efficiency after five reuse cycles, representing a recyclable MOF-based system for ratiometric cascade detection. This work establishes a design paradigm for engineering self-functionalized MOFs with tailored active sites to address multi-analyte sensing and sustainability demands.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Molecular Sensors and Ion Detection · Lanthanide and Transition Metal Complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu 221116, P. R. China
Funding
Jiangsu Normal University · Outstanding Youth Foundation of Jiangsu Province · Xuzhou Science and Technology Program · Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions
References (54)
Show source-provided references
1. Geng · Nature · 2023 · 619 · 24810.1038/d41586-023-02153-z ↗
2. Huang · Coord. Chem. Rev. · 2022 · 450 · 21423610.1016/j.ccr.2021.214236 ↗
3. Adeel · Environ. Int. · 2019 · 127 · 78510.1016/j.envint.2019.03.022 ↗
4. Metallothioneins and related chelators , ed. A. Sigel , H. Sigel and R. Sigel , Met. Ions Life Sci. , 2015
5. Rim · Saf. Health Work · 2013 · 4 · 1210.5491/SHAW.2013.4.1.12 ↗
6. Laatiaoui · Eur. Phys. J. D · 2012 · 66 · 23210.1140/epjd/e2012-30221-3 ↗
7. Liang · Spectrochim. Acta, Part B · 2005 · 60 · 12510.1016/j.sab.2004.11.010 ↗
8. Cui · Chem. Rev. · 2012 · 112 · 112610.1021/cr200101d ↗
9. Lustig · Chem. Soc. Rev. · 2017 · 46 · 324210.1039/C6CS00930A ↗
10. Ji · ACS Appl. Mater. Interfaces · 2023 · 15 · 5179610.1021/acsami.3c12705 ↗
11. Zhao · Chem. Soc. Rev. · 2021 · 50 · 448410.1039/D0CS00955E ↗
12. Zhang · Coord. Chem. Rev. · 2018 · 354 · 2810.1016/j.ccr.2017.06.007 ↗
13. Huangfu · Dalton Trans. · 2021 · 50 · 342910.1039/D0DT04276E ↗
14. Razavi · Coord. Chem. Rev. · 2020 · 415 · 21329910.1016/j.ccr.2020.213299 ↗
15. Hou · Inorg. Chem. · 2016 · 55 · 1058010.1021/acs.inorgchem.6b01809 ↗
16. Wang · J. Mater. Chem. A · 2017 · 5 · 838510.1039/C7TA01066D ↗
17. Liu · Chem. Commun. · 2014 · 50 · 873110.1039/C4CC03049D ↗
18. Ji · Nanomaterials · 2023 · 13 · 278410.3390/nano13202784 ↗
19. Chen · J. Am. Chem. Soc. · 2008 · 130 · 671810.1021/ja802035e ↗
20. Zhang · Chem. Eng. J. · 2022 · 443 · 13653210.1016/j.cej.2022.136532 ↗
21. Zhou · Inorg. Chem. · 2013 · 52 · 808210.1021/ic400770j ↗
22. Wang · ACS Food Sci. Technol. · 2022 · 2 · 191110.1021/acsfoodscitech.2c00278 ↗
23. Yang · Anal. Chem. · 2017 · 89 · 193010.1021/acs.analchem.6b04421 ↗
24. Xie · J. Phys. Chem. C · 2023 · 127 · 122010.1021/acs.jpcc.2c07084 ↗
25. Yao · Chem. – Eur. J. · 2018 · 24 · 319210.1002/chem.201705328 ↗
26. Zhang · J. Am. Chem. Soc. · 2014 · 136 · 724110.1021/ja502643p ↗
27. Zhao · Dalton Trans. · 2016 · 45 · 1488810.1039/C6DT02169G ↗
28. Liu · Chem. Commun. · 2015 · 51 · 167710.1039/C4CC08945F ↗
29. Xie · Chem · 2018 · 4 · 191110.1016/j.chempr.2018.05.017 ↗
30. Yang · Small · 2021 · 17 · 200532710.1002/smll.202005327 ↗
31. Jiang · J. Am. Chem. Soc. · 2013 · 135 · 1393410.1021/ja406844r ↗
32. Shustova · J. Am. Chem. Soc. · 2013 · 135 · 1332610.1021/ja407778a ↗
33. Mei · Angew. Chem., Int. Ed. · 2024 · 63 · e20240220510.1002/anie.202402205 ↗
34. Yin · J. Colloid Interface Sci. · 2024 · 664 · 55110.1016/j.jcis.2024.03.042 ↗
35. Cao · Chem. Commun. · 2013 · 49 · 689710.1039/c3cc43168a ↗
36. Li · Inorg. Chem. Front. · 2019 · 6 · 112910.1039/C8QI01406J ↗
37. Yan · Acc. Chem. Res. · 2017 · 50 · 278910.1021/acs.accounts.7b00387 ↗
38. Cui · Coord. Chem. Rev. · 2014 · 273–274 · 7610.1016/j.ccr.2013.10.023 ↗
39. Zhao · J. Mater. Chem. C · 2020 · 8 · 1273910.1039/D0TC03430D ↗
40. Clegg · Coord. Chem. Rev. · 2022 · 455 · 21435510.1016/j.ccr.2021.214355 ↗
41. Dalal · Inorg. Chim. Acta · 2023 · 550 · 12140610.1016/j.ica.2023.121406 ↗
42. Jia · Talanta · 2022 · 236 · 12287710.1016/j.talanta.2021.122877 ↗
43. Carlucci · Chem. – Eur. J. · 2010 · 16 · 1232810.1002/chem.201001256 ↗
44. Burrows · Chem. Commun. · 2010 · 46 · 506710.1039/c0cc00646g ↗
45. Hou · Chem. Commun. · 2011 · 47 · 1073110.1039/c1cc14115e ↗
46. Deacon · Coord. Chem. Rev. · 1980 · 33 · 22710.1016/S0010-8545(00)80455-5 ↗
47. Luo · Chem. Eng. J. · 2022 · 391 · 12353510.1016/j.cej.2019.123535 ↗
48. Wang · Angew. Chem., Int. Ed. · 2022 · 61 · e20220260410.1002/anie.202202604 ↗
49. Wen · Angew. Chem., Int. Ed. · 2023 · 62 · e20230910810.1002/anie.202309108 ↗
50. Liu · Nat. Commun. · 2022 · 13 · 551510.1038/s41467-022-33271-3 ↗
51. Binnemans · Chem. Rev. · 2009 · 109 · 428310.1021/cr8003983 ↗
52. Rao · J. Am. Chem. Soc. · 2013 · 135 · 1555910.1021/ja407219k ↗
53. Yin · J. Am. Chem. Soc. · 2019 · 141 · 1516610.1021/jacs.9b06755 ↗
54. Yi · Inorg. Chem. · 2018 · 57 · 265410.1021/acs.inorgchem.7b03053 ↗