Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles
Source abstract
Abstract
In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (kapp = 0.965 min-1) for the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Materials Science and Engineering, Beijing Institute of Technology, No. 5, Zhongguancun South Street, Beijing 100081, China
Experimental Center for Advanced Materials, Beijing Institute of Technology, No. 5, Zhongguancun South Street, Beijing 100081, China
Université Paris-Saclay, ENS Paris-Saclay, CNRS, Photophysique et Photochimie Supramoléculaires et Macromoléculaires, 91190, Gif-sur-Yvette, France
Perkinelmer Management (Shanghai) Co., Ltd, No. 1670, Zhangheng Road, Shanghai, 201203, China
Funding
National Natural Science Foundation of China · Natural Science Foundation of Beijing Municipality
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