Macroscopic chiral symmetry breaking in gelation of Fmoc-amino acids: homochiral selective secondary nucleation promoted by the choice of solvent or stirring
Source abstract
Abstract
-Fmoc-protected phenylalanine (2) or tryptophan (3) was found to spontaneously afford a gel enriched in either the L- or the D-form of their enantiomers stochastically. Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the observed phenomenon.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supramolecular Self-Assembly in Materials · Surface Chemistry and Catalysis · Chemical Synthesis and Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Research Center for Macromolecules & Biomaterials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
Funding
Japan Society for the Promotion of Science
References (30)
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