Photochemical synthesis of group 10 metal nanoclusters for electrocatalysis
Source abstract
Abstract
Four group 10 metal nanoclusters, Ni10(4-MePhS)20, Ni11(PhS)22, Pd9(PhS)18 and Pd10(PhS)20 were synthesized from disulfides based on a photochemical reduction-oxidation cascade process, which proceeds via a different mechanism to that of the conventional two-step reduction process. The as-obtained nanoclusters possess oxidative resistance and structural robustness under different conditions. Their atomically precise structures are determined to be nickel or palladium rings in which the metal atoms are bridged by Ar-S groups. Their catalytic performance in oxygen reduction reaction was compared, and the ring size-dependent catalytic activity of the group 10 metal nanoclusters was revealed. This work provides an efficient route to atomically precise and structurally stable group 10 metal nanoclusters, and sheds light on their further applications in electrocatalysis.
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanocluster Synthesis and Applications · Advanced Nanomaterials in Catalysis · Quantum Dots Synthesis And Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, P. R. China
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, P. R. China
Technology Center, China Tobacco Anhui Industrial Co., Ltd, 9 Tianda Road, Hefei 230088, P. R. China
College of Materials and Chemical Engineering, West Anhui University, Lu'an, Anhui 237015, P. R. China
Funding
Natural Science Foundation of Anhui Province · National Natural Science Foundation of China
References (55)
Show source-provided references
1. Jin · Chem. Rev. · 2021 · 121 · 56710.1021/acs.chemrev.0c00495 ↗
2. Du · Chem. Rev. · 2020 · 120 · 52610.1021/acs.chemrev.8b00726 ↗
3. Yamazoe · Acc. Chem. Res. · 2014 · 47 · 81610.1021/ar400209a ↗
4. Guan · Angew. Chem., Int. Ed. · 2022 · 61 · e20220972510.1002/anie.202209725 ↗
5. Boronat · Acc. Chem. Res. · 2014 · 47 · 83410.1021/ar400068w ↗
6. Yan · Acc. Chem. Res. · 2018 · 51 · 308410.1021/acs.accounts.8b00371 ↗
7. Yang · CCS Chem. · 2022 · 4 · 6610.31635/ccschem.021.202101188 ↗
8. Yao · Acc. Chem. Res. · 2018 · 51 · 133810.1021/acs.accounts.8b00065 ↗
9. Gan · Acc. Chem. Res. · 2018 · 51 · 277410.1021/acs.accounts.8b00374 ↗
10. Hossain · Acc. Chem. Res. · 2018 · 51 · 311410.1021/acs.accounts.8b00453 ↗
11. Tang · Acc. Chem. Res. · 2018 · 51 · 279310.1021/acs.accounts.8b00380 ↗
12. Agrachev · Acc. Chem. Res. · 2019 · 52 · 4410.1021/acs.accounts.8b00495 ↗
13. Konishi · Acc. Chem. Res. · 2018 · 51 · 312510.1021/acs.accounts.8b00477 ↗
14. Chakraborty · Chem. Rev. · 2017 · 117 · 820810.1021/acs.chemrev.6b00769 ↗
15. Nieto-Ortega · Acc. Chem. Res. · 2018 · 51 · 281110.1021/acs.accounts.8b00376 ↗
16. Eswaramoorthy · J. Phys. Chem. C · 2022 · 126 · 44410.1021/acs.jpcc.1c09453 ↗
17. Doud · Chem. – Eur. J. · 2019 · 25 · 1084010.1002/chem.201903053 ↗
18. Shimamoto · Chem. Sci. · 2022 · 13 · 411510.1039/D1SC06935G ↗
19. Jacob · Chem. Commun. · 2020 · 56 · 818210.1039/D0CC01699C ↗
20. Zou · Chin. Chem. Lett. · 2023 · 34 · 10739010.1016/j.cclet.2022.03.113 ↗
21. Srinivasan · Inorg. Chem. · 2023 · 62 · 187510.1021/acs.inorgchem.2c01292 ↗
22. Glaser · Angew. Chem., Int. Ed. · 2020 · 59 · 1026610.1002/anie.201915762 ↗
23. Falivene · ACS Catal. · 2018 · 8 · 563710.1021/acscatal.8b00042 ↗
24. Meemken · Chem. Rev. · 2017 · 117 · 1152210.1021/acs.chemrev.7b00272 ↗
25. Li · Acc. Chem. Res. · 2021 · 54 · 227510.1021/acs.accounts.1c00122 ↗
26. Suzuki · Angew. Chem., Int. Ed. · 2011 · 50 · 672210.1002/anie.201101379 ↗
27. Sun · ACS Catal. · 2021 · 11 · 1050810.1021/acscatal.1c02433 ↗
28. Zhuang · Angew. Chem., Int. Ed. · 2022 · 61 · e20220875110.1002/anie.202208751 ↗
29. Wang · J. Am. Chem. Soc. · 2018 · 140 · 627110.1021/jacs.7b13193 ↗
30. Fan · Angew. Chem., Int. Ed. · 2023 · 62 · e20221574110.1002/anie.202215741 ↗
31. Zhang · Nano Lett. · 2023 · 23 · 23510.1021/acs.nanolett.2c04163 ↗
32. Zhang · J. Am. Chem. Soc. · 2023 · 145 · 1216410.1021/jacs.3c01961 ↗
33. Liu · Nat. Commun. · 2023 · 14 · 373010.1038/s41467-023-39462-w ↗
34. Yang · J. Catal. · 2021 · 401 · 20610.1016/j.jcat.2021.07.023 ↗
35. Zhu · Precis. Chem. · 2023 · 1 · 17510.1021/prechem.3c00003 ↗
36. Yu · Adv. Funct. Mater. · 2004 · 14 · 117810.1002/adfm.200305145 ↗
37. Yao · J. Am. Chem. Soc. · 2015 · 137 · 350610.1021/jacs.5b01676 ↗
38. Herbani · AIP Conf. Proc. · 2022 · 2652 · 02000410.1063/5.0106549 ↗
39. Wang · ACS Nano · 2023 · 17 · 1160710.1021/acsnano.3c02005 ↗
40. Zhu · Nano Lett. · 2023 · 23 · 750810.1021/acs.nanolett.3c02026 ↗
41. Yan · Small · 2022 · 18 · 220081210.1002/smll.202200812 ↗
42. Seong · Angew. Chem., Int. Ed. · 2021 · 60 · 1456310.1002/anie.202102887 ↗
43. Wu · Angew. Chem., Int. Ed. · 2023 · 62 · e20230682210.1002/anie.202306822 ↗
44. Liu · Angew. Chem., Int. Ed. · 2022 · 61 · e20220562610.1002/anie.202205626 ↗
45. Tang · Angew. Chem., Int. Ed. · 2023 · 62 · e20230055310.1002/anie.202300553 ↗
46. Gao · J. Am. Chem. Soc. · 2022 · 144 · 525810.1021/jacs.2c00725 ↗
47. Yuan · Angew. Chem., Int. Ed. · 2021 · 60 · 1434510.1002/anie.202103060 ↗
48. Sun · ACS Catal. · 2021 · 11 · 1155110.1021/acscatal.1c02193 ↗
49. Shi · CCS Chem. · 2023 · 5 · 115410.31635/ccschem.022.202201960 ↗
50. Zou · Chem. Sci. · 2021 · 12 · 366010.1039/D0SC05923D ↗
51. Chen · Angew. Chem., Int. Ed. · 2009 · 48 · 438610.1002/anie.200901185 ↗
52. Jones · J. Phys. Chem. C · 2018 · 122 · 1772610.1021/acs.jpcc.8b01106 ↗
53. Zhu · Nanoscale · 2014 · 6 · 1419510.1039/C4NR04981K ↗
54. Shao · Chem. Rev. · 2016 · 116 · 359410.1021/acs.chemrev.5b00462 ↗
55. Zhao · Chem. Soc. Rev. · 2020 · 49 · 221510.1039/C9CS00869A ↗