A bioinspired metal–organic approach to cross-linked functional 3D nanofibrous hydro- and aero-gels with effective mixture separation of nucleobases by molecular recognition
Source abstract
Abstract
The direct reaction between Cu(CH3COO)2 and uracil-1-acetic acid in water gives rise to the formation of a hydrogel consisting of entangled nanometric ribbons of a crystalline antiferromagnetic 1D Cu(ii) coordination polymer (CP) decorated with biocompatible uracil nucleobases. This hydrogel is the precursor for the preparation of a meso/macroporous ultralight aerogel that shows a remarkable Young's modulus. As a proof-of-concept of the molecular recognition capability of the terminal uracil moieties anchored at Cu(ii) CP chains, this material has been tested as the selective stationary phase for the separation of nucleobase derivatives in HPLC columns.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Supramolecular Self-Assembly in Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Inorganic Chemistry
Autonomous University of Madrid
E-28049 Madrid
Spain
University of the Basque Country (UPV/EHU)
P.O. Box 644, E-48080
Bilbao
Department of Organic Chemistry II
Instituto de Ciencia Molecular (ICMol)
Parque Científico
Universidad de Valencia
46980 Paterna
Research in Chemical Sciences at UAM (IADCHEM). Universidad Autónoma de Madrid
Funding
Ministerio de Economía y Competitividad · Eusko Jaurlaritza · Generalitat Valenciana
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