journal article·2023

Dissociative reactions of [Au 25 (SR) 18 ] − at copper oxide nanoparticles and formation of aggregated nanostructures

Jayoti Roy, Biswajit Mondal, Gaurav Vishwakarma, Nonappa, Nishanthi Vasanthi Sridharan, Pattabiraman Krishnamurthi, Thalappil Pradeep

Nanoscale· Volume 15· Issue 18
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Abstract

(PET = 2-phenylethanethiolate), and polydispersed copper oxide nanoparticles with an average diameter of 50 nm under ambient conditions. These interparticle reactions result in the formation of alloy NCs and copper-doped NC fragments, which assemble to form nanospheres at the end of the reaction. High-resolution electrospray ionization mass spectrometry (ESI MS), transmission electron microscopy (HR-TEM), electron tomography, and X-ray photoelectron spectroscopy (XPS) studies were performed to understand the structures formed. The results from our study show that interparticle reactions can be extended to a range of chemical systems, leading to diverse alloy NCs and self-assembled colloidal superstructures.
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Research context

OpenAlex topics: Nanocluster Synthesis and Applications · Gold and Silver Nanoparticles Synthesis and Applications · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

DST Unit of Nanoscience (DST UNS) & Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India

Faculty of Engineering and Natural Sciences, Tampere University, FI-33720 Tampere, Finland

International Centre for Clean Water, 2nd Floor, B-Block, IIT Madras Research Park, Kanagam Road, Taramani, Chennai 600113, India

Funding

Department of Science and Technology, Ministry of Science and Technology, India · Indian Institute of Technology Madras · Academy of Finland

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