journal article·2022Open access

Magnetic nanoribbons with embedded cobalt grown inside single-walled carbon nanotubes

Denis M. Krichevsky, Lei Shi, Vladimir S. Baturin, Dmitry V. Rybkovsky, Yangliu Wu, Pavel V. Fedotov, Elena D. Obraztsova, Pavel O. Kapralov, Polina V. Shilina, Kayleigh Fung, Craig T. Stoppiello, Vladimir I. Belotelov, Andrei Khlobystov, Alexander I. Chernov

Nanoscale· Volume 14· Issue 5

Abstract

Molecular magnetism and specifically magnetic molecules have recently gained plenty of attention as key elements for quantum technologies, information processing, and spintronics. Transition to the nanoscale and implementation of ordered structures with defined parameters is crucial for advanced applications. Single-walled carbon nanotubes (SWCNTs) provide natural one-dimensional confinement that can be implemented for encapsulation, nanosynthesis, and polymerization of molecules into nanoribbons. Recently, the formation of atomically precise graphene nanoribbons inside SWCNTs has been reported. However, there have been only a limited amount of approaches to form ordered magnetic structures inside the nanotube channels and the creation of magnetic nanoribbons is still lacking. In this work we synthesize and reveal the properties of cobalt-phthalocyanine based nanoribbons (CoPcNRs) encapsulated in SWCNTs. Raman spectroscopy, transmission electron microscopy, absorption spectroscopy, and density functional theory calculations allowed us to confirm the encapsulation and to reveal the specific fingerprints of CoPcNRs. The magnetic properties were studied by transverse magnetooptical Kerr effect measurements, which indicated a strong difference in comparison with the pristine unfilled SWCNTs due to the impact of Co incorporated atoms. We anticipate that this approach of polymerization of encapsulated magnetic molecules inside SWCNTs will result in a diverse class of protected low-dimensional ordered magnetic materials for various applications.
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Research context

OpenAlex topics: Graphene research and applications · Carbon Nanotubes in Composites · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Center for Photonics and 2D Materials, Moscow Institute of Physics and Technology (MIPT), Dolgoprudny, 141701, Russia

Russian Quantum Center, 30, Bolshoy Bulvar, building 1, Skolkovo Innovative Center, Moscow region, 143026, Russian Federation

State Key Laboratory of Optoelectronic Materials and Technologies, Nanotechnology Research Center, Guangzhou Key Laboratory of Flexible Electronic Materials and Wearable Devices, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China

Vernadsky Institute of Geochemistry and Analytical Chemistry of Russian Academy of Sciences, 19, Kosygina street, Moscow, 119991, Russia

Skolkovo Institute of Science and Technology, 3, Nobel street, Moscow, 143026, Russian Federation

A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, 38, Vavilov street, Moscow, 119991, Russian Federation

School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK

Nanoscale and Microscale Research Centre, University of Nottingham, University Park, Nottingham, NG7 2RD, UK

Photonic and Quantum technologies school, Lomonosov Moscow State University, Leninskie gori, 119991 Moscow, Russia

NTI Center for Quantum Communications, National University of Science and Technology MISiS, 4, Leninskiy pr., Moscow, 119049, Russia

Funding

Ministry of Science and Higher Education of the Russian Federation · Natural Science Foundation of Guangdong Province · National Natural Science Foundation of China · Russian Foundation for Basic Research · Russian Science Foundation

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