Reversible transformation between Au 14 Ag 8 and Au 14 Ag 4 nanoclusters
Source abstract
Abstract
Although several approaches have been exploited to trigger the structural transformation of metal nanoclusters, most cases are assigned to the unidirectional conversion, while the reversible conversion of nanoclusters remains challenging. In this work, the reversible conversion between two Au-Ag alloy nanoclusters, Au14Ag8(Dppm)6(CN)4Cl4 and Au14Ag4(Dppm)6Cl4, has been accomplished, which was tracked by UV-vis and ESI-MS spectroscopy. The condition of the nanocluster reversible conversion has been meticulously mapped out. Our results provide some new insights into the cluster transformation, which will benefit the future preparation of metalloid clusters with customized structures and properties.
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanocluster Synthesis and Applications · Advanced Nanomaterials in Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei 230601, P. R. China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Anhui University, Ministry of Education, Hefei 230601, P. R. China
Institutes of Physical Science and Information Technology, Anhui University, Hefei, Anhui 230601, P. R. China
Funding
Ministry of Education of the People's Republic of China · National Natural Science Foundation of China
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