journal article·2014

Towards waste free organic synthesis using nanostructured hybrid silicas

Rosaria Ciriminna, Laura M. Ilharco, Valerica Pandarus, Alexandra Fidalgo, François Béland, Mario Pagliaro

Nanoscale· Volume 6· Issue 12
Publisher page

Abstract

As catalysis and organic synthesis come together again, the need for stable, selective and truly heterogeneous solid catalysts for clean and efficient synthetic organic chemistry has increased. Hybrid silica glasses obtained by the sol-gel nanochemistry approach can be successfully used for the waste-free synthesis of valued chemicals in various applications. This success derives from the deliberate chemical design of hybrid nanostructures capable of immobilizing and stabilizing organocatalytic species and unstable metal nanoparticles. The highly selective activity along with a broad scope and ease of application of these mesoporous materials to high-throughput reactions opens the route to faster, cleaner and more convenient processes for both small and large scale manufacturing of useful molecules.
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Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Catalytic Processes in Materials Science · Catalysis and Oxidation Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Istituto per lo Studio dei Materiali Nanostrutturati

CNR

90146 Palermo, Italy

Centro de Química-Física Molecular and IN-Institute of Nanoscience and Nanotechnology

Instituto Superior Técnico

1049-001 Lisboa, Portugal

SiliCycle Inc.

Québec City, Canada

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