Rapid formation of small mixed-valence luminescent silver clusters via cation-coupled electron-transfer in a redox-active porous ionic crystal based on dodecamolybdophosphate
Source abstract
Abstract
Redox-active porous ionic crystals based on polyoxometalate (POM) were utilized to form and stabilize small mixed-valence luminescent silver clusters via cation-coupled electron-transfer (CCET) reactions. Reduction-induced ion-exchange between Cs+ and Ag+via CCET took less than 1 min to complete and consisted of two steps: electron transfer from reduced POM to Ag+ and the subsequent formation of a silver cluster, and diffusion of the silver cluster and exchange with Cs+. Notably, the simple ion-exchange took more than 24 h. The compound containing the silver cluster showed high affinity toward unsaturated hydrocarbon guests.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polyoxometalates: Synthesis and Applications · Metal-Organic Frameworks: Synthesis and Applications · Nanocluster Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Basic Science
School of Arts and Sciences
The University of Tokyo
Tokyo 153-8902
Japan
Division of Chemistry
Graduate School of Science
Kyoto University
Kyoto 606-8502
JEOL RESONANCE Inc.
Tokyo 196-8558
Molecular Photoscience Research Center
Kobe University
Kobe 657-8501
Funding
Ministry of Education, Culture, Sports, Science and Technology
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