journal article·2015

Atom precise platinum–thiol crowns

Anu George, K. S. Asha, Arthur C. Reber, Scott R. Biltek, Anthony F. Pedicini, Ayusman Sen, Shiv N. Khanna, Sukhendu Mandal

Nanoscale· Volume 7· Issue 46
Publisher page

Abstract

Ligand stabilized water soluble Pt nanoclusters were synthesized and characterized through electrospray ionization mass spectrometry. Glutathione was used as the ligand, and Pt5(SG)10, and Pt6(SG)12 clusters were synthesized. Theoretical investigations found that these clusters do not possess a metal core, but rather are most stable in a ring structure. The clusters are stabilized through the thiol ligands forming a square planar structure around each Pt atom to form a ring. The structural elucidation was confirmed through UV/Vis and IR spectroscopy.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nanocluster Synthesis and Applications · Gold and Silver Nanoparticles Synthesis and Applications · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry

Indian Institute of Science Education and Research Thiruvananthapuram

Thiruvananthapuram, India

Department of Physics

Virginia Commonwealth University

Richmond, USA

Department of Chemistry

The Pennsylvania State University

University Park

, USA

Funding

Science and Engineering Research Board · Basic Energy Sciences

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