Binary solvent-mediated modulation of two-dimensional nanoconfined catalytic behaviors
Source abstract
Abstract
Inspired by natural enzymes, the fabricated two-dimensional graphene oxide-based membrane reactors offer promising nanoconfined catalytic ability and mass transfer efficiency. Interestingly, for the ring-opening reaction of styrene oxide with aniline as the model reaction, abrupt modulation of nanoconfined catalytic behaviors was found by introducing binary solvents into the membrane reactors. In detail, in a binary solvent composed of ethanol and another solvent, the conversion dropped abruptly from ≈100% to less than 1% with a very small decrease in ethanol content in a certain range. Synergistic coordination of multiple physicochemical factors was explored to explain this novel modulation of nanoconfined catalytic behaviors.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Enzyme Catalysis and Immobilization · Nanomaterials for catalytic reactions · Graphene research and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratory of Bio-inspired Smart Interface Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Suzhou Institute for Advanced Research, University of Science and Technology of China, Jiangsu 215123, P. R. China
Funding
Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China
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