Controllable synthesis of hollow mesoporous organosilica nanoparticles with pyridine-2,6-bis-imidazolium frameworks for CO ₂ conversion

A series of hard-template-derived hollow mesoporous organosilica nanoparticles (HMONs) with pyridine-2,6-bis-imidazolium frameworks have been described for the first time. As a part of the investigation, to evaluate the effects of the hard template nature, the Si/CTAB and organosilica/TEOS molar ratios, and the stepwise addition of precursors, four reaction conditions denoted as methods A-D were designed. In the presence of polystyrene latex as a hard template, the HMONs that we wished to synthesize were not yielded with a Si/CTAB molar ratio of 3 (method A), but we could synthesize the desired HMONs with a Si/CTAB molar ratio of 9 and an organosilica : TEOS ratio of 1 : 99 (method B). The ratio of organosilica to TEOS could be improved up to 2.5 : 97.5 if the precursor additions are made in a stepwise manner rather than by simultaneous additions (method C). Using sSiO₂ as a hard template, a yolk-shell morphology was observed by adopting a Si/CTAB molar ratio of 3 (method D). The HMONs were modified by iodide ions and their activity was explored toward the coupling of CO₂ with epoxides. Among the catalysts, I-HMON-L-C-2.5 exhibited excellent results under mild reaction conditions. Well-oriented pore sizes and short channel length facilitated easy mass transfer from one side and the integration of the interior hollow regions of the catalyst particles from the other side improved the CO₂ retention time around pores where the imidazolium organocatalysts were located, which made I-HMON-L-C-2.5 an effective catalyst for title CO₂ utilization. The catalyst was reused at least six times without exhibiting any changes in its activity. HMONs can also be used as solid CNC ligands for the preparation of copper catalysts for the click reaction between phenyl acetylene and benzyl azide.