Aminotriazine derived N-doped mesoporous carbon with a tunable nitrogen content and their improved oxygen reduction reaction performance
Source abstract
Abstract
RHE. The characterisation results of the prepared materials indicated that pyridinic and graphitic nitrogen in the carbon framework promoted ORR activity with improved four-electron selectivity and excellent methanol tolerance and stability. DFT calculations demonstrated that the structural and planar defects in the N-doped carbon regulated the surface electronic properties of the electrocatalyst, leading to a reduction in the energy barrier for the ORR activity. This strategy has the potential to unlock a platform for designing a series of catalysts for electrochemical applications.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Nanomaterials for catalytic reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Global Innovative Centre for Advanced Nanomaterials (GICAN), School of Engineering, The University of Newcastle, Callaghan, New South Wales 2308, Australia
Department of Physics, School of Advanced Sciences, Vellore Institute of Technology, Vellore, India
Singapore Synchrotron Light Source, National University of Singapore, 119260, Singapore
Funding
Australian Research Council · National Research Foundation Singapore
References (51)
Show source-provided references
1. Guo · Science · 2016 · 351 · 36110.1126/science.aad0832 ↗
2. Kim · Angew. Chem., Int. Ed. · 2018 · 57 · 1713510.1002/anie.201811061 ↗
3. Wei · Catalysts · 2015 · 5 · 157410.3390/catal5031574 ↗
4. Wang · New J. Chem. · 2017 · 41 · 739210.1039/C7NJ01178D ↗
5. Wang · Inorg. Chem. Front. · 2017 · 4 · 123110.1039/C7QI00233E ↗
6. Liu · Proc. Natl. Acad. Sci. U. S. A. · 2023 · 120 · e230326212010.1073/pnas.2303262120 ↗
7. Liu · Nano Res. Energy · 2023 · 2 · e912004910.26599/NRE.2023.9120049 ↗
8. Zhang · J. Phys. Chem. C · 2011 · 115 · 1117010.1021/jp201991j ↗
9. Kim · Small · 2020 · 16 · 190357210.1002/smll.201903572 ↗
10. Lakhi · Chem. Soc. Rev. · 2017 · 46 · 7210.1039/C6CS00532B ↗
11. Bello · Microporous Mesoporous Mater. · 2017 · 252 · 5010.1016/j.micromeso.2017.06.021 ↗
12. Yan · Adv. Funct. Mater. · 2024 · 231610010.1002/adfm.202316100 ↗
13. Yan · Proc. Natl. Acad. Sci. U. S. A. · 2021 · 118 · e211003611810.1073/pnas.2110036118 ↗
14. Fang · Precis. Chem. · 2023 · 1 · 39510.1021/prechem.3c00059 ↗
15. Selvarajan · Adv. Energy Sustainability Res. · 2021 · 2 · 210010410.1002/aesr.202100104 ↗
16. Wutscher · ChemElectroChem · 2019 · 6 · 51410.1002/celc.201801217 ↗
17. Xing · ACS Nano · 2014 · 8 · 685610.1021/nn501506p ↗
18. Mu · Biomass Convers. Biorefin. · 2019 · 9 · 40110.1007/s13399-019-00378-5 ↗
19. Panangattu Dharmarajan · Adv. Energy Mater. · 2024 · 240068610.1002/aenm.202400686 ↗
20. Dontsova · Chem. Mater. · 2015 · 27 · 517010.1021/acs.chemmater.5b00812 ↗
21. Fawaz · Carbon · 2023 · 214 · 11834510.1016/j.carbon.2023.118345 ↗
22. Yang · Angew. Chem., Int. Ed. · 2011 · 50 · 533910.1002/anie.201100170 ↗
23. Chu · Small · 2023 · 19 · 230287510.1002/smll.202302875 ↗
24. Chu · Battery Energy · 2023 · 2 · 2022004110.1002/bte2.20220041 ↗
25. Sathish · Angew. Chem., Int. Ed. · 2021 · 60 · 2124210.1002/anie.202108605 ↗
26. Mane · Angew. Chem., Int. Ed. · 2017 · 56 · 848110.1002/anie.201702386 ↗
27. Kumar · Chem. Soc. Rev. · 2023 · 52 · 760210.1039/D3CS00213F ↗
28. Li · Proc. Natl. Acad. Sci. U. S. A. · 2023 · 120 · e221826112010.1073/pnas.2218261120 ↗
29. Kim · Chem. – Asian J. · 2021 · 16 · 399910.1002/asia.202101069 ↗
30. Guan · J. Mater. Chem. A · 2023 · 11 · 1283710.1039/D3TA00318C ↗
31. Park · Chem. – Eur. J. · 2017 · 23 · 1075310.1002/chem.201702566 ↗
32. Lee · Chem. Commun. · 2014 · 50 · 681810.1039/c4cc00146j ↗
33. Schwarz · Adv. Mater. · 2017 · 29 · 110.1002/adma.201703399 ↗
34. Margolese · Chem. Mater. · 2000 · 12 · 244810.1021/cm0010304 ↗
35. Miyahara · Thin Solid Films · 2006 · 499 · 1310.1016/j.tsf.2005.07.046 ↗
36. Vinu · Appl. Catal., A · 2005 · 281 · 20710.1016/j.apcata.2004.11.031 ↗
37. Joseph · J. Mol. Catal. A: Chem. · 2003 · 206 · 1310.1016/S1381-1169(03)00452-7 ↗
38. Kresse · Phys. Rev. B: Condens. Matter Mater. Phys. · 1996 · 54 · 1116910.1103/PhysRevB.54.11169 ↗
39. Perdew · Phys. Rev. Lett. · 1996 · 77 · 386510.1103/PhysRevLett.77.3865 ↗
40. Blöchl · Phys. Rev. B: Condens. Matter Mater. Phys. · 1994 · 50 · 1795310.1103/PhysRevB.50.17953 ↗
41. Grimme · J. Comput. Chem. · 2006 · 27 · 178710.1002/jcc.20495 ↗
42. Akikubo · Carbon · 2020 · 169 · 30710.1016/j.carbon.2020.07.027 ↗
43. Park · Chem. – Eur. J. · 2017 · 23 · 1075310.1002/chem.201702566 ↗
44. Sheng · ACS Nano · 2011 · 5 · 435010.1021/nn103584t ↗
45. Sathish · Adv. Sci. · 2022 · 9 · 210560310.1002/advs.202105603 ↗
46. Selvarajan · Adv. Energy Sustainability Res. · 2021 · 2 · 210010410.1002/aesr.202100104 ↗
47. Lazar · J. Phys. Chem. C · 2019 · 123 · 1069510.1021/acs.jpcc.9b02163 ↗
48. Matanovic · J. Phys. Chem. C · 2016 · 120 · 2922510.1021/acs.jpcc.6b09778 ↗
49. Higgins · J. Phys. Chem. C · 2010 · 114 · 2198210.1021/jp106814j ↗
50. Wang · ACS Catal. · 2012 · 2 · 78110.1021/cs200652y ↗
51. Chen · J. Phys. Chem. C · 2009 · 113 · 2100810.1021/jp908067v ↗