journal article·2022

Helically aligned fused carbon hollow nanospheres with chiral discrimination ability

Jun Maruyama, Shohei Maruyama, Yukiyasu Kashiwagi, Mitsuru Watanabe, Tsutomu Shinagawa, Toru Nagaoka, Toshiyuki Tamai, Naoya Ryu, Koichi Matsuo, Mao Ohwada, Koki Chida, Takeharu Yoshii, Hirotomo Nishihara, Fumito Tani, Hiroshi Uyama

Nanoscale· Volume 14· Issue 10
Publisher page

Abstract

While the functions of carbon materials with precisely controlled nanostructures have been reported in many studies, their chiral discriminating abilities have not been reported yet. Herein, chiral discrimination is achieved using helical carbon materials devoid of chiral attachments. A Fe3O4 nanoparticle template with ethyl cellulose (carbon source) is self-assembled on dispersed multiwalled carbon nanotubes (MWCNTs) fixed in a lamellar structure, with helical nanoparticle alignment induced by the addition of a binaphthyl derivative. Carbonization followed by template removal produces helically aligned fused carbon hollow nanospheres (CHNSs) with no chiral molecules left. Helicity is confirmed using vacuum-ultraviolet circular dichroism spectroscopy. Chiral discrimination, as revealed by the electrochemical reactions of binaphthol and a chiral ferrocene derivative in aqueous and nonaqueous electrolytes, respectively, is attributable to the chiral space formed between the CHNS and MWCNT surfaces.
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Research context

OpenAlex topics: Graphene research and applications · Mesoporous Materials and Catalysis · Surface Chemistry and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Osaka Research Institute of Industrial Science and Technology, 1-6-50, Morinomiya, Joto-ku, Osaka 536-8553, Japan

Kumamoto Industrial Research Institute, 3-11-38, Higashimachi, Higashi-ku, Kumamoto 862-0901, Japan

Hiroshima Synchrotron Radiation Center, Hiroshima University, 2-313 Kagamiyama, Higashi-Hiroshima 739-0046, Japan

Advanced Institute for Materials Research, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai, 980-8577, Japan

Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai, 980-8577, Japan

Institute for Materials Chemistry and Engineering, Kyushu University, 744, Motooka, Nishi-ku, Fukuoka 819-0395, Japan

Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita 565-0871, Japan

Funding

Japan Society for the Promotion of Science · Core Research for Evolutional Science and Technology · Nippon Sheet Glass Foundation for Materials Science and Engineering

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