journal article·2022

Operating interfaces to synthesize L1 0 -FePt@Bi-rich nanoparticles by modifying the heating process

Ling Chang, Chun Wu, Qunshou Wang, Ting Li, Dong Zhao, Kai Wang, Qiang Wang, Wenli Pei

Nanoscale· Volume 14· Issue 32
Publisher page

Abstract

A facile strategy to operate interfaces when synthesizing L10-FePt@Bi-rich nanoparticles (NPs) has been proposed. Two interfaces are indispensable to obtain the high ordering L10-FePt structure. One is the mismatched interfaces between the initial γ-PtBi2 nuclei and the disordered fcc-FePt phase. The other is the in situ grown coherent interfaces between the L10-FePt and Bi-rich phases. Increasing the heating rates when the temperature rises from 120 °C to 310 °C benefits the formation of mismatched interfaces and improves the uniformity of phases and composition in NPs. Reducing the heating rate at higher temperature ensures sufficient time for Bi to diffuse across the coherent interface, which facilitates the disorder-order transition of L10-FePt NPs. This study provides a new perspective on operating interfaces during the wet-chemical synthesis process.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic properties of thin films · Theoretical and Computational Physics · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819, China

School of Metallurgy, Northeastern University, Shenyang 110819, China

Key Laboratory of Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China

School of Materials Science and Engineering, Liaoning Technical University, Fuxin, 123000, China

Funding

Department of Education of Liaoning Province · National Key Research and Development Program of China · Liaoning Revitalization Talents Program · National Natural Science Foundation of China

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