A six-fold difference in structure results in a six-order difference in conductivity: silica shell nanoarchitectonics on carbon black particles
Source abstract
Abstract
Carbon black (Ketchen Black with a particle size of several tens of nm) was coated with silica with a varied thickness of 2 and 12 nm. Carbon/silica core-shell particles were grafted with the γ-methacryloxypropylsilyl group to be homogeneously dispersed into a poly(methyl methacrylate) film. The electrical conductivity of the poly(methyl methacrylate) films containing carbon/silica particles was successfully controlled by the thickness of the silica layer; silica coating with 2 nm thickness gave a conducting film, while that with 12 nm thickness gave a less conducting film with a remarkable difference on the order of 106 (in volume conductivity).
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Conducting polymers and applications · Graphene research and applications · Mesoporous Materials and Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Graduate School of Creative Science and Engineering, Waseda University, Nishiwaseda 1-6-1, Shinjuku-ku, Tokyo 169-8050, Japan
School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology (VISTEC), 555 Moo 1 Payupnai, Wangchan, Rayong 21210, Thailand
Funding
National Research Council of Thailand · New Energy and Industrial Technology Development Organization
References (49)
Show source-provided references
1. A. K.Sen , Coated Textiles Principles and Applications , CRC Press , Boca Raton , 2008
2. T.Schneller , R.Waser , M.Kosec and D.Payne , Chemical Solution Deposition of Functional Oxide Thin Films , Springer , 201310.1007/978-3-211-99311-8 ↗
3. A.Ulman , An Introduction to UItrathin Organic Films from Langmuir Blodgett to Self-Assembly , Academic Press Inc. , San Diego , 1991
4. Ogawa · Annu. Rep. Prog. Chem., Sect. C: Phys. Chem. · 1998 · 94 · 20910.1039/pc094209 ↗
5. Ghosh Chaudhuri · Chem. Rev. · 2012 · 112 · 237310.1021/cr100449n ↗
6. Ma · Acc. Chem. Res. · 2015 · 48 · 13610.1021/ar500311w ↗
7. Yang · J. Mater. Chem. B · 2013 · 1 · 244710.1039/c3tb20365d ↗
8. Bastakoti · Chem. – Asian J. · 2013 · 8 · 130110.1002/asia.201300072 ↗
9. Malgras · Bull. Chem. Soc. Jpn. · 2015 · 88 · 117110.1246/bcsj.20150143 ↗
10. Ogawa · Chem. Rec. · 2017 · 17 · 21710.1002/tcr.201600068 ↗
11. Shiba · Nanoscale · 2017 · 9 · 1679110.1039/C7NR06086F ↗
12. Bao · Microporous Mesoporous Mater. · 2016 · 227 · 12110.1016/j.micromeso.2016.02.040 ↗
13. Tan · Langmuir · 2005 · 21 · 818010.1021/la050618s ↗
14. Williamson · Chem. Commun. · 2011 · 47 · 156810.1039/C0CC04257A ↗
15. Shimura · J. Colloid Interface Sci. · 2007 · 312 · 31110.1016/j.jcis.2007.02.091 ↗
16. Zhang · Chem. Soc. Rev. · 2015 · 44 · 31510.1039/C4CS00199K ↗
17. Gawande · Chem. Soc. Rev. · 2015 · 44 · 754010.1039/C5CS00343A ↗
18. El-Toni · Nanoscale · 2016 · 8 · 251010.1039/C5NR07004J ↗
19. Hayes · J. Chromatogr. A · 2014 · 1357 · 3610.1016/j.chroma.2014.05.010 ↗
20. Sanchez-Salcedo · Chem. Eng. J. · 2018 · 340 · 11410.1016/j.cej.2017.12.116 ↗
21. Li · Inorg. Chem. · 2018 · 57 · 801210.1021/acs.inorgchem.8b01169 ↗
22. Cheepborisutikul · Inorg. Chem. · 2021 · 60 · 620110.1021/acs.inorgchem.0c03476 ↗
23. Gamonchuang · Colloids Surf., A · 2016 · 511 · 3910.1016/j.colsurfa.2016.09.080 ↗
24. K.Kinoshita , Carbon: Electrochemical and Physicochemical Properties , Wiley , 1988
25. J. E.Morris and K.Iniewski , Graphene, Carbon Nanotubes, and Nanostructures: Techniques and Applications , CRC Press , Boca Raton , 2013
26. Carbon Black: Science and Technology , ed. J.-B. Donnet , Marcel Dekker , New York , 2nd edn, 1993
27. Arabale · Chem. Phys. Lett. · 2003 · 376 · 20710.1016/S0009-2614(03)00946-1 ↗
28. Noerochim · Electrochim. Acta · 2010 · 56 · 31410.1016/j.electacta.2010.08.078 ↗
29. Gomathi · Adv. Mater. · 2005 · 17 · 275710.1002/adma.200500539 ↗
30. Deslandes · J. Mater. Sci. Lett. · 1990 · 9 · 20010.1007/BF00727715 ↗
31. Gadiou · J. Eur. Ceram. Soc. · 2008 · 28 · 226510.1016/j.jeurceramsoc.2008.02.022 ↗
32. Itatani · Carbon Nanotubes: Res. Appl. · 2010 · 8 · 125
33. Wang · Appl. Catal., B · 2005 · 56 · 30510.1016/j.apcatb.2004.09.018 ↗
34. Ntim · J. Colloid Interface Sci. · 2012 · 375 · 15410.1016/j.jcis.2012.01.063 ↗
35. Satishkumar · J. Mater. Res. · 1997 · 12 · 60410.1557/JMR.1997.0089 ↗
36. Zheng · Mater. Lett. · 2006 · 60 · 299110.1016/j.matlet.2006.02.030 ↗
37. Kim · J. Colloid Interface Sci. · 2008 · 322 · 32110.1016/j.jcis.2008.03.045 ↗
38. Ogihara · J. Solid State Chem. · 2009 · 182 · 158710.1016/j.jssc.2009.04.005 ↗
39. Kuo · Eur. Polym. J. · 2009 · 45 · 47410.1016/j.eurpolymj.2008.10.044 ↗
40. Nsib · Prog. Org. Coat. · 2006 · 55 · 30310.1016/j.porgcoat.2005.11.006 ↗
41. Wang · Carbon · 2007 · 45 · 28510.1016/j.carbon.2006.09.025 ↗
42. Kahn · Nano Lett. · 2002 · 2 · 121510.1021/nl025755d ↗
43. Fernando · Langmuir · 2004 · 20 · 477710.1021/la036217z ↗
44. Shiba · Dalton Trans. · 2016 · 45 · 1874210.1039/C6DT03524H ↗
45. Ogawa · Chem. Mater. · 2006 · 18 · 171510.1021/cm0601234 ↗
46. Ide · J. Colloid Interface Sci. · 2011 · 358 · 24510.1016/j.jcis.2011.02.018 ↗
47. Isoda · Chem. Mater. · 2000 · 12 · 170210.1021/cm0000494 ↗
48. Hiroshima · Jpn. J. Appl. Phys. · 1994 · 33 · 39510.1143/JJAP.33.395 ↗
49. Shimura · J. Mater. Sci. · 2007 · 42 · 529910.1007/s10853-007-1771-y ↗