In situ insertion of copper to form heteroanionic D 3h -symmetric [Cu 3 Mo 8 O 32 ] 10− for a templated Ag 55 nanocluster
Source abstract
Abstract
A polyoxometalate-templated thiolate-protected silver nanocluster, [Cu3(Mo4O16)2@Ag55(CyhS)43(CH3O)(COOCF3)]·3H2O, has been isolated under solvothermal conditions. In situ insertion of three Cu2+ ions into two polymolybdate anions generated a new, sandwich-type D3h-symmetric [Cu3(Mo4O16)2]10- polyoxoanion template encapsulated into an Ag55(CyhS)43 shell. The structure and composition of this Ag nanocluster have been fully characterized. This work has provided a new way to develop high-nuclearity metal nanoclusters with various structures.
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanocluster Synthesis and Applications · Advanced Nanomaterials in Catalysis · Polyoxometalates: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), Institute of Chemistry and Culture, School of Chemistry & Material Science, Shanxi Normal University, Taiyuan 030006, P. R. China
Key Laboratory of Interface Science and Engineering in Advanced Material (Ministry of Education), College of Chemistry & Chemical Engineering, Taiyuan University of Technology, Taiyuan, 030024, P. R. China
Funding
National Natural Science Foundation of China
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