journal article·2022

Tailored synthesis of molecularly thin platinum nanosheets using designed 2D surfactant solids

Eisuke Yamamoto, Akiko Suzuki, Makoto Kobayashi, Minoru Osada

Nanoscale· Volume 14· Issue 32
Publisher page

Abstract

The assembly of the surfactants has been utilized as unique templates for the controlled synthesis of metal nanosheets. However, current strategies for metal nanosheets have mainly focused on the liquid-phase surfactant assembly. Herein, we found the solid-state surfactants as designable crystals suitable for nanostructural control and proposed a novel synthetic route for molecularly thin Pt metal nanosheets using solid surfactant crystals as a precursor. The 2D surfactant crystals containing planarly arranged Pt complexes were prepared, and the subsequent UV-ozone treatment and reduction process allowed us to obtain Pt metal nanosheets. Pt metal nanosheets had a distinct morphology with various thicknesses (from 1.5 nm to 3.0 nm), characteristic of 2D surfactant crystals.
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Research context

OpenAlex topics: Molecular Junctions and Nanostructures · Gold and Silver Nanoparticles Synthesis and Applications · Surface Chemistry and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Chemistry & Institute of Materials and Systems for Sustainability (IMaSS), Nagoya University, Nagoya 464-8601, Japan

Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), Saitama 332-0012, Japan

International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan

Funding

Japan Science and Technology Corporation · Japan Society for the Promotion of Science

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