journal article·2021

A flexible Mn 0.5 Ti 2 (PO 4 ) 3 /C nanofiber film with superior cycling stability for potassium-ion batteries

Jing Dai, Die Su, Jianping Yang, Wen Zhang, Qianfu Wang, Li Liu, Hai Hu, Huifang Li, Zhiming Liu

Nanoscale· Volume 13· Issue 47
Publisher page

Abstract

First-principles calculations indicate that Mn0.5Ti2(PO4)3 is more suited to potassium-ion storage because of its lower energy gap than that of KTi2(PO4)3. A flexible Mn0.5Ti2(PO4)3/C nanofiber film (F-MTP/C NFF) has been first synthesized via electrospinning and applied to potassium-ion batteries as a self-standing anode. An integral carbon conductive network, unique one-dimensional nanostructure, and exceptional mechanical flexibility give F-MTP/C NFF outstanding potassium-ion storage performance. Impressively, the self-standing F-MTP/C NFF electrode delivers a high specific capacity of 218 mA h g-1 at 0.02 A g-1 and shows ultra-long cycling stability of 2000 cycles at 1 A g-1. This work may give a new insight into developing NASICON-type Ti-based materials as flexible electrodes for potassium-ion batteries.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Base for International Science & Technology Cooperation, National Local Joint Engineering Laboratory for Key materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, China

College of Electromechanical Engineering, Shandong Engineering Laboratory for Preparation and Application of High-performance Carbon-Materials, Qingdao University of Science & Technology, Qingdao, Shandong 266061, China

Funding

Ministry of Education of the People's Republic of China · Higher Education Discipline Innovation Project · Natural Science Foundation of Shandong Province · National Natural Science Foundation of China

References (70)

Show source-provided references
1. Ke · Energy Storage Mater. · 2020 · 26 · 31310.1016/j.ensm.2019.08.029 ↗
2. Hu · Chem. Mater. · 2015 · 27 · 666810.1021/acs.chemmater.5b02471 ↗
3. Roh · RSC Adv. · 2014 · 4 · 3167210.1039/C4RA04943H ↗
4. Lian · Nano Energy · 2017 · 40 · 110.1016/j.nanoen.2017.08.002 ↗
5. Fei · J. Power Sources · 2018 · 399 · 29410.1016/j.jpowsour.2018.07.124 ↗
6. Zhao · Energy Environ. Sci. · 2020 · 13 · 24610.1039/C9EE03250A ↗
7. Feng · Energy Environ. Mater. · 2020 · 4 · 45110.1002/eem2.12126 ↗
8. Zhang · Energy Environ. Sci. · 2021 · 14 · 96510.1039/D0EE03203D ↗
9. Yang · Energy Storage Mater. · 2019 · 23 · 52210.1016/j.ensm.2019.04.008 ↗
10. Hwang · Adv. Funct. Mater. · 2018 · 28 · 180293810.1002/adfm.201802938 ↗
11. Goodenough · Mater. Res. Bull. · 1976 · 11 · 20310.1016/0025-5408(76)90077-5 ↗
12. Masquelier · Chem. Rev. · 2013 · 113 · 655210.1021/cr3001862 ↗
13. Ni · ACS Energy Lett. · 2020 · 5 · 176310.1021/acsenergylett.0c00702 ↗
14. Zhang · Nano Energy · 2019 · 60 · 43210.1016/j.nanoen.2019.03.085 ↗
15. Wang · J. Power Sources · 2003 · 124 · 23110.1016/S0378-7753(03)00609-8 ↗
16. Huang · J. Power Sources · 2015 · 294 · 65010.1016/j.jpowsour.2015.06.143 ↗
17. Liu · J. Power Sources · 2009 · 189 · 70610.1016/j.jpowsour.2008.08.050 ↗
18. Zhao · ACS Appl. Mater. Interfaces · 2017 · 9 · 470910.1021/acsami.6b14196 ↗
19. He · Nano Energy · 2021 · 82 · 10576410.1016/j.nanoen.2021.105764 ↗
20. Yang · Solid State Ionics · 2018 · 314 · 6110.1016/j.ssi.2017.11.016 ↗
21. Han · Chem. Commun. · 2016 · 52 · 1166110.1039/C6CC06177J ↗
22. Leonard · ACS Energy Lett. · 2018 · 3 · 37310.1021/acsenergylett.8b00009 ↗
23. Wei · Adv. Energy Mater. · 2018 · 8 · 180110210.1002/aenm.201801102 ↗
24. Wang · ACS Appl. Mater. Interfaces · 2016 · 8 · 223810.1021/acsami.5b11003 ↗
25. Voronina · Small · 2020 · 16 · 200109010.1002/smll.202001090 ↗
26. Zhang · Adv. Funct. Mater. · 2018 · 28 · 180268410.1002/adfm.201802684 ↗
27. Srout · ChemSusChem · 2019 · 12 · 484610.1002/cssc.201902002 ↗
28. Wei · ACS Appl. Mater. Interfaces · 2016 · 8 · 3533610.1021/acsami.6b12650 ↗
29. Zhan · J. Mater. Sci.: Mater. Electron. · 2018 · 29 · 4250
30. Liu · Adv. Mater. · 2020 · 32 · 200050510.1002/adma.202000505 ↗
31. Chen · Sci. China Mater. · 2021 · 64 · 54710.1007/s40843-020-1465-8 ↗
32. Gong · ACS Nano · 2020 · 14 · 1405710.1021/acsnano.0c06690 ↗
33. Yao · ACS Nano · 2019 · 13 · 469510.1021/acsnano.9b00980 ↗
34. Xia · Energy Storage Mater. · 2019 · 17 · 110.1016/j.ensm.2018.08.005 ↗
35. Xia · Chem. Eng. J. · 2021 · 413 · 12740010.1016/j.cej.2020.127400 ↗
36. Qiu · Energy Environ. Sci. · 2020 · 13 · 57110.1039/C9EE03682B ↗
37. Lakshmi · J. Alloys Compd. · 2021 · 857 · 15826710.1016/j.jallcom.2020.158267 ↗
38. Atangana Etogo · Energy Storage Mater. · 2020 · 24 · 16710.1016/j.ensm.2019.08.022 ↗
39. Suo · Chem. Eng. J. · 2020 · 388 · 12439610.1016/j.cej.2020.124396 ↗
40. Huang · ChemSusChem · 2017 · 10 · 470410.1002/cssc.201701484 ↗
41. Peng · ACS Appl. Mater. Interfaces · 2017 · 9 · 2980410.1021/acsami.7b08804 ↗
42. Luo · Nano-Micro Lett. · 2019 · 11 · 6310.1007/s40820-019-0294-9 ↗
43. Blöchl · Phys. Rev. B: Condens. Matter Mater. Phys. · 1994 · 50 · 1795310.1103/PhysRevB.50.17953 ↗
44. Perdew · Phys. Rev. Lett. · 1996 · 77 · 386510.1103/PhysRevLett.77.3865 ↗
45. Grimme · J. Comput. Chem. · 2006 · 27 · 178710.1002/jcc.20495 ↗
46. Stevanović · Phys. Rev. B: Condens. Matter Mater. Phys. · 2012 · 85 · 11510410.1103/PhysRevB.85.115104 ↗
47. Monkhorst · Phys. Rev. B: Condens. Matter Mater. Phys. · 1976 · 13 · 518810.1103/PhysRevB.13.5188 ↗
48. Kresse · Phys. Rev. B: Condens. Matter Mater. Phys. · 1996 · 54 · 1116910.1103/PhysRevB.54.11169 ↗
49. Kresse · Comput. Mater. Sci. · 1996 · 6 · 1510.1016/0927-0256(96)00008-0 ↗
50. Su · Nano-Micro Lett. · 2021 · 13 · 10710.1007/s40820-021-00632-4 ↗
51. Huang · Compos. Sci. Technol. · 2009 · 69 · 199110.1016/j.compscitech.2009.05.006 ↗
52. Choi · Electrochim. Acta · 2016 · 210 · 58810.1016/j.electacta.2016.05.190 ↗
53. Liu · J. Alloys Compd. · 2018 · 742 · 49010.1016/j.jallcom.2018.01.262 ↗
54. Nie · Nano-Micro Lett. · 2018 · 10 · 7110.1007/s40820-018-0225-1 ↗
55. Jung · Energy Environ. Sci. · 2011 · 4 · 134510.1039/c0ee00620c ↗
56. Liu · J. Power Sources · 2015 · 293 · 56210.1016/j.jpowsour.2015.05.092 ↗
57. Weng · J. Mater. Chem. A · 2017 · 5 · 1176410.1039/C7TA00482F ↗
58. Hao · Mater. Res. Bull. · 2018 · 97 · 1310.1016/j.materresbull.2017.08.023 ↗
59. Hu · J. Mater. Chem. A · 2016 · 4 · 749510.1039/C6TA01928E ↗
60. Liu · Appl. Catal., B · 2017 · 201 · 11910.1016/j.apcatb.2016.08.031 ↗
61. Su · J. Mater. Chem. A · 2020 · 8 · 2066610.1039/D0TA06327D ↗
62. Xing · J. Mater. Chem. A · 2019 · 7 · 576010.1039/C8TA12497C ↗
63. Yao · Adv. Mater. · 2018 · 30 · e180523410.1002/adma.201805234 ↗
64. Zhou · Adv. Funct. Mater. · 2020 · 30 · 200387110.1002/adfm.202003871 ↗
65. Mauger · Mater. Sci. Eng., R · 2018 · 134 · 110.1016/j.mser.2018.07.001 ↗
66. Wang · Energy Environ. Sci. · 2020 · 13 · 458310.1039/D0EE01638A ↗
67. Su · Appl. Surf. Sci. · 2021 · 541 · 14838810.1016/j.apsusc.2020.148388 ↗
68. Su · Adv. Funct. Mater. · 2017 · 27 · 160554410.1002/adfm.201605544 ↗
69. Tao · Energy Storage Mater. · 2020 · 27 · 21210.1016/j.ensm.2020.02.004 ↗
70. Tsai · Chem. Eng. J. · 2021 · 417 · 12855210.1016/j.cej.2021.128552 ↗