Assembly by solvent evaporation: equilibrium structures and relaxation times

(N = 21). We derive explicit formulas for the process and rigorously compute relaxation times, which drastically increase when the packing parameter reaches the hard-sphere liquid-solid transition η = 0.49. This result shows that contrary to what occurs in an evaporation of a single component system, the relaxation times are not determined by the diffusion constant of the vapor, but rather, are dominated by the residence time of solvent molecules trapped within the capping ligands. Our theory provides a number of predictions that enable the design of new structures while improving the control and quality of their assembly.