Insights into the effect of surface coordination on the structure and properties of Au ₁₃ Cu ₂ nanoclusters

Comparable systems are of great significance for understanding the structure-property relationship. Herein, a new Au₁₃Cu₂ nanocluster protected by phenylethanethiol (PET) and triphenylphosphine (TPP) is synthesized and structurally determined, including an icosahedral Au₁₃ and two CuS₃ configurations. Based on previous work, a comparable system was formed-only the surface coordination of Cu atoms changes from Cu-N to Cu-S, which results in a tremendous change in the optical properties. Based on this, the effect of the coordination mode on the structure and optical properties was primarily investigated in both experiment and theory. And the results demonstrate that changing the coordination mode from Cu-N to Cu-S has a significant effect on the electronic structure. This work will offer new insights into ligand engineering.