Tuning the ease of formation of on-surface metal-adatom coordination polymers featuring diketones
Source abstract
Abstract
We use pyrene-4,5,9,10-tetraketone molecules with substituents of varying bulkiness in the 2,7 positions to probe the generality and versatility of the previously reported on-surface coordination of two diketones with a single metal atom, leading to one-dimensional coordination polymers. Three different low index surfaces of group 11 metals (Cu, Ag and Au) are used to provide both the support and the metal atoms for metal-organic coordination. By real space visualisation with single molecule resolution employing scanning tunnelling microscopy we investigate the molecular self-assembly and show how this can be substantiated with the formation of metal-organic linear and cyclic oligomers, depending on the employed substrate.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Surface Chemistry and Catalysis · Machine Learning in Materials Science · Block Copolymer Self-Assembly
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Physics Department E20
Technical University of Munich
D-85748 Garching
Germany
POLYMAT
University of the Basque Country UPV/EHU
E-20018 Donostia-San Sebastian
Spain
Ikerbasque
Funding
H2020 Future and Emerging Technologies · FP7 Ideas: European Research Council · China Scholarship Council · FP7 People: Marie-Curie Actions · Technische Universität München · Ikerbasque, Basque Foundation for Science · Euskal Herriko Unibertsitatea · Deutsche Forschungsgemeinschaft · Ministerio de Economía y Competitividad · Ekonomiaren Garapen eta Lehiakortasun Saila, Eusko Jaurlaritza · H2020 European Research Council
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