journal article·2022-03

Experimental investigation and thermodynamic optimization of the Al–Ni–Sc ternary system

Haotian Miao, Ligang Zhang, Libin Liu, Zixuan Deng, Hang Wang, Patrick J. Masset

Calphad· Volume 76
Publisher page

Abstract

Phase equilibria of the Al–Ni–Sc system were investigated by combination of key experiments and thermodynamic modeling. The isothermal sections of the Al–Ni–Sc ternary system in the (Al, Ni)-rich region at 873K and 673K were investigated using the electron probe microanalysis (EPMA) and X-ray diffraction (XRD). The solubilities of the binary phases in the ternary system were measured. According to the experimental results in this work and related literature, the Al–Ni–Sc ternary system has been optimized by means of the CALPHAD (CALculation of PHAse Diagrams) method. Isothermal sections at 1273, 1173, 873 and 673 K were reproduced. The calculated thermodynamic and phase equilibria data for the ternary system agree well with the experimental data. This work can be used as a basis for the multi-component thermodynamic database of Al-based alloys.
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Research context

OpenAlex topics: Intermetallics and Advanced Alloy Properties · Advanced Materials Characterization Techniques · nanoparticles nucleation surface interactions

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References (43)

Show source-provided references
1. The role of alloying elements in the design of nickel-base superalloys10.1007/BF00549796 ↗
2. Synthesis, structure, and mechanical properties of Ni–Al and Ni–Cr–Al superalloy foams10.1016/j.actamat.2003.11.012 ↗
3. Microstructure and yield strength of SLM-fabricated CM247LC Ni-Superalloy10.1016/j.actamat.2017.02.007 ↗
4. Effects of minor Sc addition on the microstructure and mechanical properties of 7055 Al alloy during aging10.1016/j.msea.2017.12.067 ↗
5. Examination of the effect of Sc on 2000 and 7000 series aluminium alloy castings: for improvements in fusion welding10.1016/S0921-5093(02)00942-5 ↗
6. Microstructure and mechanical properties of the alloys NiAl and NiAl–28Cr–6Mo doped with rare-earth Sc
7. A thermodynamic assessment of the Mg–Sn–Sb ternary system10.1016/j.calphad.2021.102361 ↗
8. Experimental investigation of the phase relations in the Fe-Zr-Y ternary system
9. Thermodynamic modeling of the Al-Cr-Ni system over the entire composition and temperature range10.1016/j.jallcom.2016.07.130 ↗
10. Study of rare earth crystals and alloys
11. Phase diagram and properties of aluminum-scandium alloys
12. The Alt-Sc (aluminum-scandium) system10.1007/BF02882170 ↗
13. Al-Sc (aluminium-scandium)
14. Thermodynamic analysis of Al–Sc, Cu–Sc and Al–Cu–Sc system10.1016/j.jallcom.2009.10.003 ↗
15. Phase diagrams of Sc-(Co, Ni, Cu) systems
16. Binary alloy phase diagrams
17. Phase equilibria in the nickel-aluminium-scandium system at 1000 °C10.1016/0022-5088(68)90142-2 ↗
18. Maslenkov · 1984 · 203
20. Al-Sc (Aluminum-Scandium)10.1361/105497100770340093 ↗
21. Thermodynamic assessment of the Ni–Sc binary system10.1016/j.calphad.2014.11.005 ↗
22. The investigation of the system scandium–nickel–aluminium in the range 0–0.333 (0–33.3%) of Scandium
23. Ferro · 1993 · vol. 7 · 463
24. Experimental investigation of phase equilibria in the Al–Ni–Sc system10.1007/s10853-019-03640-3 ↗
25. Crystal structure of ternary compounds ScCoAl and ScNiAl
26. Ternary compounds with the Mg6Cu16Si7 type structure in some systems of two transition metals with aluminium and gallium
27. Crystal structure of scandium nickel dialuminium, ScNiAl2 with MgCuAl2 type10.1524/zkri.1992.198.3-4.291 ↗
28. Ternary aluminides R0.67Ni2Al6 (R=Sc, Y, Gd–Lu) with partly disordered structures10.1016/j.jssc.2012.09.031 ↗
29. Massalski · 1990
30. NiAl3: a structure type of its own?10.1107/S0108767396086655 ↗
31. Phase formation during dissolution of nickel in liquid aluminium
32. ScT2X and LnT2X compounds with the MnCu2al-type structure10.1016/0022-5088(87)90376-6 ↗
33. Thermodynamic modeling of the Al–Nb–V system10.1016/j.calphad.2021.102321 ↗
34. Experimental study and thermodynamic modeling of the Cu–Sn–Si–O system and sub-systems10.1016/j.calphad.2021.102312 ↗
35. Experimental investigation of diffusion behaviors in γ and γ’ Ni–Al–Co alloys10.1016/j.calphad.2021.102286 ↗
36. Effect of hot extrusion on microstructure and tribological behavior of Al2O3p reinforced 7075 aluminum-matrix composites10.1007/s11771-021-4768-9 ↗
37. Thermodynamic properties of the Al-Fe-Ni system acquired via a hybrid approach combining calorimetry, first-principles and CALPHAD10.1016/j.actamat.2009.07.031 ↗
38. Algebraic representation of thermodynamic properties and the classification of solutions10.1021/ie50458a036 ↗
39. Thermodynamic optimization of the Ni–Al–Nd ternary system
40. Using the PARROT module of Thermo-Calc with the Cr–Ni system as example10.1016/j.calphad.2016.10.003 ↗
41. PANDAT software with PanEngine, PanOptimizer and PanPrecipitation for multi-component phase diagram calculation and materials property simulation10.1016/j.calphad.2008.08.004 ↗
42. (*=equal Contributions), the Materials Project: a materials genome approach to accelerating materials innovation
43. Experimental investigation and thermodynamic modeling of the Mg–Sn–Sr ternary system