Experimental investigation and thermodynamic calculation of the Fe–Si–Bi system
Source abstract
Abstract
Phase relationship of the Fe–Si–Bi ternary system was established by optical microscope, scanning electron microscope in combination with energy dispersive spectroscopy and X–ray diffraction. Isothermal sections of the Fe–Si–Bi system at 973 and 1173 K consist of 3 and 4 three–phase equilibrium regions, respectively. The liquid phase is in equilibrium with all the Fe–Si phases. No ternary compound is found and Bi is almost insoluble in the Fe–Si phases. Combining the reliable thermodynamic data from literature with the current experimental work, phase relationship of the Fe–Si–Bi system have been thermodynamically extrapolated. The calculated results are in good agreement with the experimental results.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metallurgical and Alloy Processes · Magnetic Properties of Alloys · Intermetallics and Advanced Alloy Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (39)
Show source-provided references
1. Perspectives on coated advanced high strength steels for automotive applications
2. Reactive wetting during hot-dip galvanizing of high manganese alloyed steel10.1016/j.surfcoat.2010.11.053 ↗
3. Reactive wetting of high Mn steels during continuous hot-dip galvanizing10.1016/j.actamat.2011.02.027 ↗
4. Microstructure and mechanical properties of Fe–0.2C–5Mn steel processed by art-annealing10.1016/j.msea.2011.05.039 ↗
5. Challenges in hot dip galvanizing of high strength dual phase steel: surface selective oxidation and mechanical property degradation10.1016/j.surfcoat.2012.02.001 ↗
6. The role of surface oxides on annealed high strength steels in hot-dip galvanizing10.1016/j.corsci.2013.01.039 ↗
7. Supra-ductile and high–strength manganese–TRIP/TWIP steels for high energy absorption purposes10.2355/isijinternational.43.438 ↗
8. Influence of gas atmosphere dew point on the galvannealing of CMnSi TRIP steel10.1007/s11661-013-1867-8 ↗
9. Surface selective oxidation of Sn-added CMnSi TRIP steel10.1007/s11661-016-3331-z ↗
10. Influence of minor alloying elements on selective oxidation and reactive wetting of CMnSi TRIP steel during hot dip galvanizing10.1007/s11661-014-2394-y ↗
11. The effect of Bi on the selective oxide formation on CMnSi TRIP steel10.1007/s11661-016-3735-9 ↗
12. Fratesi · 2000
13. Fratesi · 2001
14. Zinc solubility measurements and thermodynamic evaluation of Zn–Pb–Bi ternary system10.1179/cmq.2006.45.1.117 ↗
15. Thermodynamic optimization of the lead-free solder system Bi–In–Sn–Zn10.1016/S0925-8388(03)00325-6 ↗
16. Gagne · 1997
17. Contemporary use of Ni and Bi in hot-dip galvanizing10.1016/S0257-8972(02)00137-8 ↗
18. An assessment of the Fe–C–Si system10.1007/BF02664987 ↗
19. Experimental and thermodynamic studies of the Fe–Si binary system10.2355/isijinternational.52.540 ↗
20. The re-assessment of the Mg-Zn and Fe-Si systems and their incorporation in thermodynamic descriptions of the Al-Mg-Zn and Fe-Si-Zn systems10.1016/j.calphad.2013.07.007 ↗
21. Critical reassessment of the Fe–Si system10.1016/j.calphad.2016.11.003 ↗
22. The ternary Fe–Sb–Si system: experimental phase diagram study and thermodynamic calculation10.1016/j.calphad.2018.08.008 ↗
23. Experimental investigation and thermodynamic calculation of the Fe–Si–Sn system10.1016/j.calphad.2017.03.006 ↗
24. Experimental investigation and thermodynamic reassessment of the Cu–Fe–Si System10.1007/s11661-009-9877-2 ↗
25. Experimental investigation and thermodynamic reassessment of the Fe-Si-Zn system10.1016/j.calphad.2010.07.006 ↗
26. Assessment of the ternary Fe–Si–B phase diagram10.1016/j.calphad.2013.08.001 ↗
27. Comparison of solidification behavior between insitu observation and simulation of Fe–C–Si system10.1016/j.jallcom.2014.05.184 ↗
28. Thermodynamic assessment of the Fe–Mn–Si system and atomic mobility of its fcc phase10.1016/j.jallcom.2015.01.261 ↗
29. The ternary bismuth–iron–antimony system: experimental phase diagram study and thermodynamic evaluation10.1016/j.calphad.2008.01.001 ↗
30. 450° C isothermal section of the Zn–Fe–Bi ternary phase diagram10.1016/j.jallcom.2007.08.029 ↗
31. The Bi–Si (Bismuth–Silicon) system
32. Kubaschewski · 1982 · 1
33. Binary systems. Part 3: binary systems from Cs–K to Mg–Zr
34. Thermodynamic evaluation of the Fe–Zn system10.1016/S0925-8388(01)01273-7 ↗
35. SGTE data for pure elements10.1016/0364-5916(91)90030-N ↗
36. Thermodynamic assessment of the Al–Ni system10.1016/S0925-8388(96)02652-7 ↗
37. Regular–solution model for stoichiometric phases and ionic melts10.3891/acta.chem.scand.24-3618 ↗
38. Systematic of binary phase diagrams, formed by low-melting elements (Bi, Sn, Zn, In) and the metals of IV-th and V-th periods10.2298/JMMB0501079V ↗
39. Structural asymmetry in liquid Fe–Si alloys10.1080/14786431003745302 ↗