journal article·2017-02

Na-doped LiMnPO4 as an electrode material for enhanced lithium ion batteries

K RAJAMMAL, D SIVAKUMAR, NAVANEETHAN DURAISAMY, K RAMESH, S RAMESH

Bulletin of Materials Science· Volume 40· Issue 1
Publisher page

Abstract

We report the influence of sodium (Na)-incorporated lithium manganese phosphate as an active material on its performance in electrochemical study for energy storage application. Li1−x Na x MnPO4 with different mole ratios (0.00 ≤ x ≤ 0.05) of sodium is synthesized via a simple sol–gel method. The discharge capacity of Li1−x NaxMnPO4 varies with respect to mole ratios of sodium incorporated. The maximum discharge capacity of 92.45 mAh g−1 is observed in Li0.97Na0.03MnPO4, which is higher than that of pristine LiMnPO4 and other Na-incorporated LiMnPO4. The maximum cyclic stability is found to be 84.15% up to 60 cycles. These results demonstrate that Li0.97Na0.03MnPO4 plays a significant role in future energy storage application.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

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