Evaluation of styrene-based copolymers and glutaraldehyde for medium-density fiberboard production

The performance of medium density fiberboard (MDF) with styrene-based copolymers and glutaraldehyde was evaluated. Styrene/n-butyl acrylate (SBA), styrene maleic anhydride (SMA), and glutaraldehyde (GA) were tested at 1%, 2.5%, and 5% levels. Surface roughness parameters, mechanical and physical properties, and formaldehyde emission values were evaluated. Two different methods were used for panel preparation: surface application and mixing with UF resin. Different trends were observed depending on chemical types, chemical concentrations, and application methods. The surface roughness parameters (Ra, Rq, Rz) decreased with the application methods and chemicals used. The smoothest surfaces were obtained from groups with the chemicals compared to control groups. The surface application method yielded the most favorable results. The thickness swelling (TS) and water absorption (WA) values generally showed slight improvements, and better results were obtained with the UF-mixing method. Mechanical properties such as internal bond strength (IB), modulus of rupture (MOR), and modulus of elasticity (MOE) showed variations depending on the experimental parameters. In general, higher values were obtained for both application methods compared to control values. Free formaldehyde emission values were notably reduced with the UF-mixing method. In general, the use of SBA, SMA, and GA chemicals contributed to lower formaldehyde emission values.