A Universal Equation for the Emission Range of X Rays from Bulk Specimens
Source abstract
Abstract
The derivation of a universal equation to compute the range of emitted X rays is presented for homogeneous bulk materials. This equation is based on two fundamental assumptions: the φ(ρz) curve of X-ray generation is constant and the ratio of the emitted to the generated X-ray range is equal to the ratio of the emitted to the generated X-ray intensity. An excellent agreement is observed with data obtained from Monte Carlo simulations of 200,000 electron trajectories in C, Al, Cu, Ag, Au, and an Fe–B alloy with boron weight fractions equal to 0.01, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, and 0.99, performed with the electron beam energy varied from 1 to 30 keV in 1-keV steps. When the ratio of the generated X-ray range to the photon mean free path is much smaller than one, the emission X-ray range is equal to the generated X-ray range, but when this ratio is much greater than one, the emission X-ray range is constant and is given by the product of the effective photon mean free path multiplied by the sine of the take-off angle.
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Research context
OpenAlex topics: X-ray Spectroscopy and Fluorescence Analysis · Electron and X-Ray Spectroscopy Techniques · Advanced Materials Characterization Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (7)
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1. Pouchou, J.L. & Pichoir, F. (1991).Quantitative analysis of homogeneous or stratified microvolumes applying the model PAP. InElectron Probe Quantitation, Workshop at the National Bureau of Standards, Gaithersburg, Maryland, 1988, Heinrich, K.F.J. & Newbury, D.E. (Eds.), pp.31–75.New York:Plenum Press.10.1007/978-1-4899-2617-3_4 ↗
2. Gauvin, R. , Lifshin, E. , Demers, H. , Horny, P. & Campbell, H. (2006).Win X-ray: A new Monte Carlo program that computes X-ray spectra obtained with a scanning electron microscope.Microsc Microanal 12,49–64.10.1017/S1431927606060089 ↗
3. Hovington, P. , Drouin, D. , Gauvin, R. & Joy, D.C. (1997b).Parameterization of the range of electrons at low energy using the CASINO Monte Carlo program.Microsc Microanal 3(suppl. 2),885–886.10.1017/S1431927600011314 ↗
4. Anderson, C.A. & Hasler, M.F. (1966).Extension of electron microprobe techniques to biochemistry by the use of long wavelength X-rays. InProceedings of the Fourth International Conference on X-ray Optics and Microanalysis, Castaing, R. , Deschamps, P. & Philibert, J. (Eds.), pp.310–327.Paris:Hermann.
5. Henke, B.L. , Gullikwa, E.M. & Davies, J.C. (1993).X-ray interactions: Photoabsorption, scattering, transmission and reflection at E = 50–30000 eV, Z = 1–92.At Data Nucl Tables 54,181–342.10.1006/adnd.1993.1013 ↗
6. Hovington, P. , Drouin, D. & Gauvin, R. (1997a).CASINO: A new Monte Carlo Code in C language for electron beam interaction, Part I: Description of the program.Scanning 19,1–14.10.1002/sca.4950190101 ↗
7. Bastin, G.F. , Dijkstra, J.M. & Heijligers, H.J.M. (1998).PROZA96: An improved matrix correction program for electron probe microanalysis, based on a double Gaussian φ(ρz) approach.X-Ray Spectrom 27,3–10.10.1002/(SICI)1097-4539(199801/02)27:1<3::AID-XRS227>3.0.CO;2-L ↗