journal article·2015-04Open access

Synthesis of platinum nanoparticles with higher stability in ionic liquid–Nafion film and their electrocatalytic application

Qing Zhang, Dawei Pan, HaiYun Zhang, HaiTao Han

Micro & Nano Letters· Volume 10· Issue 4

Abstract

4‐(3‐methyl‐1‐imidazolio)‐1‐butanesulphonic acid triflate (BSMIMOTF)–Nafion film is introduced as a novel catalyst support. Nafion is used as the conductive membrane for BSMIMOTF immobilisation. A uniform distribution of spherical platinum nanoparticles (PtNPs) 10–30 nm in diameter can be electrochemically deposited on the membranous BSMIMOTF–Nafion matrix. Compared with the PtNPs on a bare and Nafion‐modified electrode, the proposed sulphonyl‐terminated ionic liquid (IL)–Nafion stabilised PtNPs exhibit higher electrocatalytic activity and better stability towards the electro‐oxidation of methanol. The IL–Nafion film as a new catalyst support has great potential application in direct‐methanol fuel cells.
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Research context

OpenAlex topics: Ionic liquids properties and applications · Electrochemical Analysis and Applications · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

The Key Laboratory in Molecular and Nano‐materials Probes of the Ministry of Education of China College of Chemistry Chemical Engineering and Materials Science Shandong Normal University Jinan Shandong 250014 People's Republic of China

Key Laboratory of Coastal Environmental Processes and Ecological Remediation Yantai Institute of Coastal Zone Research Chinese Academy of Sciences Yantai Shandong 264003 People's Republic of China

Shandong Provincial Key Laboratory of Coastal Zone Environmental Processes Yantai Shandong 264003 People's Republic of China

School of Chemistry and Chemistry Engineering Yantai University Yantai Shandong 264005 People's Republic of China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Shandong Province

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