journal article·2021-01Open access

Encapsulating Keggin‐H 3 PW 12 O 40 into UIO‐66(Zr) for manufacturing the biodiesel

Jiayu Zhu, Ze Wang, Xinluo Song, Bangyao Zhao, Yafeng Li, Yuanrui Wang

Micro & Nano Letters· Volume 16· Issue 1

Abstract

Abstract In the presence of acetic acid as modulated agent, Keggin‐H 3 PW 12 O 40 (K‐PW 12 ) has been encapsulated into UIO‐66(Zr) by the solvothermal method. The as‐synthesized K‐PW 12 @UIO‐66(Zr) composite has further been characterized by PXRD, TG, FTIR, ICP‐AES, N 2 isothermal adsorption, SEM and TEM. The results exhibit that Keggin‐H 3 PW 12 O 40 is entrapped into the interior cage of UIO‐66(Zr) framework which is enlarged by losing terephthalic acid linker in the presence of acetic acid. K‐PW 12 @UIO‐66(Zr) composite can efficiently catalyse the esterification of methanol and oleic acid into biodiesel.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Catalysis and Hydrodesulfurization Studies · Polyoxometalates: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemical Engineering Changchun University of Technology Changchun 130012 P. R. China

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