journal article·2022-06

Modified Unreacted Core Model for Reduction of Manganese Ore by CO Gas

Eui-Hyuk Kwon, Ji-A. Lee, Jeong-Whan Han

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Abstract

Pre-reduction of manganese ore has a direct impact on energy savings for the subsequent smelting process. To this end, knowledge of the kinetics of the pre-reduction of manganese ore is useful in controlling the process parameters for the subsequent smelting process. In this study, a kinetic model that considers the effects of temperature, ore size, and CO content during the reduction process is developed. The model was performed using an unreacted core model using similarity to iron ore. This modified unreacted core model can be used to predict the change in the state of manganese ore over time, and this can predict the change in the reduction rate depending on the process temperature, CO gas change and ore size. The rate constants of the chemical reaction of manganese ore are obtained experimentally. The results of the developed prediction model show good agreement with the experimental data and the reduction degree of manganese ore is found to increase with increasing temperature and CO content in the gas.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Iron and Steelmaking Processes · Metal Extraction and Bioleaching

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Y. Alemdag, M. Beder, Met. Mater. Int. 26, 1811 (2020)10.1007/s12540-019-00572-0 ↗
2. I. Tanabe, J. Of Metals 20, 81 (1968)10.1007/BF03378711 ↗
3. M.N. El Hazek, T.A. Lasheen, A.S. Helal, Hydrometallurgy 84, 187 (2006)10.1016/j.hydromet.2006.05.006 ↗
4. E. Eriksen, A. Lomo, in Extraction Metallurgy '85. Extraction Metallurgy '85 Symposium, London, 9-12 September 1985 (Institution of Mining and Metallurgy, Great Britain, 1985), pp. 445–472
5. O. Ostrovski, T.J.M. Webb, ISIJ Int. 35, 1331 (1995)10.2355/isijinternational.35.1331 ↗
6. J.S. Hansen, J.E. Tress, R.H. Nafziger, JOM 45, 59 (1993)10.1007/BF03223289 ↗
7. K. Dewar, J.B. See, The influence of carbonaceous reducing agents on the rate of reduction of representative manganese and chromium ores, NIM reports, Report No. 1968 (National Institute of Metallurgy, Randburg, 1978)
8. R.H. Spitzer, F.S. Manning, W.O. Phillbrook, T. Metall. Soc. AIME 236, 1715 (1966)
9. M. Tangstad, S.E. Olsen, in Proceedings of 7th International Ferroalloys Congress (INFACON 7), ed. by J.K. Tuset, H. Tveit, I.G. Page. 7th International Ferroalloys Congress, Trondheim, 11-14 June 1995 (The Norwegian Ferroalloy Research Organization (FFF), Trondheim, 1995), pp. 621–630
10. C.W. Bale, E. Belisle, P. Chartrand, S.A. Decterov, G. Eriksson, K. Hack, I.H. Jung, Y.B. Kang, J. Melancon, A.D. Pelton, C. Robelin, S. Petersen, Calphad 33, 295 (2009)10.1016/j.calphad.2008.09.009 ↗
11. T. Murayama, Y. Ono, Y. Kawai, Tetsu-to-Hagane 63, 1099 (1977)10.2355/tetsutohagane1955.63.7_1099 ↗
12. R. Takahashi, S. Kurozu, Y. Takahashi, Tetsu-to-Hagane 66, 336 (1980)10.2355/tetsutohagane1955.66.3_336 ↗
13. J.H. Kwon, E.H. Kwon, K.W. Lee, K.M. Kim, J.A. Lee, J.W. Han, Korean J. Met. Mater. 54, 847 (2016)
14. S.W. Joo, J.D. Shin, D.K. Shin, S.H. Hong, J.S. Ki, J.I. Hwnag, B.D. You, Korean J. Met. Mater. 50, 753 (2012)
15. J.H. Kim, S.W. Joo, D.J. Kim, S.Y. Kim, J.I. Hwang, H.C. Lee, B.D. You, Korean J. Met. Mater. 54, 79 (2014)
16. R. Ishak, M. Tangstad, in Proceedings of 11th International Conference on Innovations in the Ferro Alloy Industry (INFACON XI), ed. by R.K. Das, T.S. Sundaresan. 11th International Conference on Innovations in the Ferro Alloy Industry, New Delhi, 18-21 February 2007 (MacMillan, New Delhi, 2007), pp. 268-280
17. T. Bluhm-Drenhaus, E. Simsek, S. Wortz, V. Scherer, Chem. Eng. Sci. 65, 2821 (2010)10.1016/j.ces.2010.01.015 ↗
18. F. Garcia-Labiano, A. Abad, L.F. de Diego, P. Gayan, J. Adanez, Chem. Eng. Sci. 57, 2381 (2002)10.1016/S0009-2509(02)00137-9 ↗
19. W. Moffat, M.R.W. Walmsley, in Appita Annual Conference. 59th Appita Annual Conference and Exhibition, incorporating the 13th ISWFPC: International Symposium on Wood, Fibre and Pulping Chemistry, 16-19 May 2005. vol. 1 (Elsevier, Amsterdam, 2005), pp.487-494
20. C.J. Fielden, B.I. Wood, J. Iron Steel I. 206, 650 (1968)
21. Y. Gao, O.M. Martinez, H.Y. Sohn, H.G. Kim, C.W. Kim, Metall. Mater. Trans. B 43, 1465 (2012)10.1007/s11663-012-9731-6 ↗