A Green Stable Antifouling PEGylated PVDF Membrane Prepared by Vapor-Induced Phase Separation

While green solvents are being implemented in the fabrication of polyvinylidene fluoride (PVDF) membranes, most are not compatible with the vapor-induced phase separation (VIPS) process for which relatively low dissolution temperatures are required. Additionally, preparing antifouling green membranes in one step by blending the polymer with an antifouling material before inducing phase separation remains extremely challenging due to the solubility issues. Here, the green solvent triethyl phosphate (TEP) was used to solubilize both PVDF and a copolymer (synthesized from styrene monomer and poly(ethylene glycol) methyl ether methacrylate). VIPS was then used, yielding symmetric bi-continuous microfiltration membranes. For a 2 wt% copolymer content in the casting solution, the corresponding membrane P2 showed a homogeneous and dense surface distribution of the copolymer, resulting in a high hydration capacity (>900 mg/cm3) and effective resistance to biofouling during the adsorption tests using bovine serum albumin, Escherichia coli or whole blood, with a measured fouling reduction of 80%, 89% and 90%, respectively. Cyclic filtration tests using bacteria highlighted the competitive antifouling properties of the membranes with a flux recovery ratio after two water/bacterial solution cycles higher than 70%, a reversible flux decline ratio of about 62% and an irreversible flux decline ratio of 28%. Finally, these green antifouling membranes were shown to be stable despite several weeks of immersion in water.