A new prototype melt-electrospinning device for the production of biobased thermoplastic sub-microfibers and nanofibers
Source abstract
Abstract
Abstract Sub-microfibers and nanofibers have a high surface-to-volume ratio, which makes them suitable for diverse applications including environmental remediation and filtration, energy production and storage, electronic and optical sensors, tissue engineering, and drug delivery. However, the use of such materials is limited by the low throughput of established manufacturing technologies. This short report provides an overview of current production methods for sub-microfibers and nanofibers and then introduces a new melt-electrospinning prototype based on a spinneret with 600 nozzles, thereby providing an important step towards larger-scale production. The prototype features an innovative collector that achieves the optimal spreading of the fiber due to its uneven surface, as well as a polymer inlet that ensures even polymer distribution to all nozzles. We prepared a first generation of biobased fibers with diameters ranging from 1.000 to 7.000 μm using polylactic acid and 6% ( w /w) sodium stearate, but finer fibers could be produced in the future by optimizing the prototype and the composition of the raw materials. Melt electrospinning using the new prototype is a promising method for the production of high-quality sub-microfibers and nanofibers.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Advanced Sensor and Energy Harvesting Materials · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Aachen-Maastricht Institute for Biobased Materials (AMIBM), Maastricht University, Brightlands Chemelot Campus, Urmonderbaan 22, Geleen 6167, RD, The Netherlands.
References (100+)
Show source-provided references
1. Back S. The role of nanotechnology in sustainable textiles. BLACKBURN R. S.: Sustainable Textiles. Woodhead Publishing. 2009. 978–1–84569-453-1 p. 302–304.
2. DIN CEN ISO/TS 80004–1: Nanotechnologien – Fachwörterverzeichnis – Teil 1: Kernbegriffe (ISO/TS 80004–1:2015); Deutsche Fassung CEN ISO/TS 80004–1:2015.
3. DIN CEN ISO/TS 80004–2: Nanotechnologien – Fachwörterverzeichnis – Teil 2: Nanoobjekte (ISO/TS 80004–2:2015); Deutsche Fassung CEN ISO/TS 80004–2:2017.
4. Brown T, Dalton P, Hutmacher DW, et al. Melt electrospinning today: an opportune time for an emerging polymer process. Elsevier. 2016;56:116–166. 1:CAS:528:DC%2BC28XhslSkurc%3D
5. 10.4172/2324-8777.1000e10810.4172/2324-8777.1000e108 ↗
6. 10.1016/j.proeng.2013.11.03410.1016/j.proeng.2013.11.034 ↗
7. 10.1021/am200748y10.1021/am200748y ↗
8. 10.1016/j.marpolbul.2016.03.03710.1016/j.marpolbul.2016.03.037 ↗
9. 10.1016/j.mser.2011.06.00110.1016/j.mser.2011.06.001 ↗
10. 10.1016/j.nanoen.2012.11.01410.1016/j.nanoen.2012.11.014 ↗
11. Zhang G Zheng J Liang R et al. α-MnO2/carbon nanotube/carbon nanofiber composite catalytic air electrodes for rechargeable lithium-air batteries. jes.ecsdl.org 2011; 158: A822.10.1149/1.3590736 ↗
12. 10.1021/nn302654p10.1021/nn302654p ↗
13. 10.1021/nl020216u10.1021/nl020216u ↗
14. 10.1016/j.biotechadv.2010.01.00410.1016/j.biotechadv.2010.01.004 ↗
15. 10.2217/nnm.13.13210.2217/nnm.13.132 ↗
16. 10.1177/204173141244353010.1177/2041731412443530 ↗
17. 10.1089/biores.2016.002210.1089/biores.2016.0022 ↗
18. 10.1088/1468-6996/11/1/01410810.1088/1468-6996/11/1/014108 ↗
19. 10.1016/j.biomaterials.2008.01.01110.1016/j.biomaterials.2008.01.011 ↗
20. 10.1016/j.addr.2009.07.00710.1016/j.addr.2009.07.007 ↗
21. 10.1002/app.4288310.1002/app.42883 ↗
22. 10.1002/jbm.b.3084110.1002/jbm.b.30841 ↗
23. 10.2147/nano.2006.1.1.1510.2147/nano.2006.1.1.15 ↗
24. 10.2174/13816120677902632610.2174/138161206779026326 ↗
25. 10.1016/j.addr.2009.07.01310.1016/j.addr.2009.07.013 ↗
26. 10.1016/j.jconrel.2015.10.04910.1016/j.jconrel.2015.10.049 ↗
27. Zamani M, Prabhakaran MP, Ramakrishna S. Advances in drug delivery via electrospun and electrosprayed nanomaterials. Int J Nanomedicine. 2013;8:2997–3017.
28. 10.2174/138161282166615030215195910.2174/1381612821666150302151959 ↗
29. 10.1016/j.jconrel.2015.09.00810.1016/j.jconrel.2015.09.008 ↗
30. Zeng J, Xu X, Chen X, et al. Biodegradable electrospun fibers for drug delivery. Elsevier. 2003;92:227–231. 1:CAS:528:DC%2BD3sXot1Srs7c%3D
31. 10.1002/jbm.b.3004110.1002/jbm.b.30041 ↗
32. Hu X, Liu S, Zhou G, et al. Electrospinning of polymeric nanofibers for drug delivery applications. Elsevier. 2014;185:12–21. 1:CAS:528:DC%2BC2cXpvFWktr4%3D
33. Kenawy E, Abdel-Hay, El-Newehy MH, et al. Processing of polymer nanofibers through electrospinning as drug delivery systems. Elsevier. 2009;113:296–302. 1:CAS:528:DC%2BD1cXhsVersL%2FI
34. 10.1016/j.ijpharm.2011.01.05810.1016/j.ijpharm.2011.01.058 ↗
35. Pillay V Dott C Choonara Y et al. A review of the effect of processing variables on the fabrication of electrospun nanofibers for drug delivery applications. hindawi.com 2013; 2013: 22.10.1155/2013/789289 ↗
36. 10.1007/s40204-017-0064-z10.1007/s40204-017-0064-z ↗
37. 10.1039/C6BM00070C10.1039/C6BM00070C ↗
38. 10.1002/adfm.20130074610.1002/adfm.201300746 ↗
39. 10.1002/smll.20110043610.1002/smll.201100436 ↗
40. 10.1002/adma.20120015510.1002/adma.201200155 ↗
41. Kwnry Lim CT: Nanofiber technology: current status and emerging developments. In: Topical Volume on Advanced Polymeric Materials Bd. 2017; 70: 1–17.10.1016/j.progpolymsci.2017.03.002 ↗
42. Blim A, Jarecki L, Blonski S. Modeling of pneumatic melt drawing of polypropylene super-thin fibers in the Laval nozzle. Bull Pol Ac. 2014;62:42–54.
43. NANOVAL GMBH & CO KG: Nanoval - Process. https://www.nanoval.de/index.php. Accessed 17 Oct 2018.
44. 10.1021/nl101355x10.1021/nl101355x ↗
45. 10.1002/app.3027510.1002/app.30275 ↗
46. 10.1063/1.495890510.1063/1.4958905 ↗
47. Masuda M Funakoshi J. Island-in-sea fiber combined filament yarn and textile product. EP2821533A1 2012.
48. 10.1016/j.cis.2011.11.00110.1016/j.cis.2011.11.001 ↗
49. 10.1016/j.addr.2007.04.02210.1016/j.addr.2007.04.022 ↗
50. 10.1021/ar00050a00210.1021/ar00050a002 ↗
51. 10.1088/0022-3727/37/2/01910.1088/0022-3727/37/2/019 ↗
52. 10.1088/0022-3727/33/11/30110.1088/0022-3727/33/11/301 ↗
53. 10.1063/1.140826010.1063/1.1408260 ↗
54. 10.1002/adma.20040071910.1002/adma.200400719 ↗
55. 10.1016/S1369-7021(06)71389-X10.1016/S1369-7021(06)71389-X ↗
56. Ahn YC Park SK Kim GT Hwang XY Lee CG et al. Development of high efficiency nanofilters made of nanofibers. Nano Korea 2004 Symposium on NT Challenge 2006; 6(6): 1030–1035.10.1016/j.cap.2005.07.013 ↗
57. 10.1002/asia.20100043610.1002/asia.201000436 ↗
58. 10.1364/OE.16.01081510.1364/OE.16.010815 ↗
59. Bajakova J Chaloupek J et al. “Drawing”- The production of individual nanofibers by experimental method. Nanocon. 2011.
60. Ndaro MS, Jin X, Chen T, et al. Splitting of islands-in-the-sea fibers ( PA6/COPET ) during hydroentangling of nonwovens. J Eng Fiber Fabr. 2007;2:1–9.
61. 10.1002/marc.20060062410.1002/marc.200600624 ↗
62. 10.1021/ie00084a02110.1021/ie00084a021 ↗
63. 10.1007/s12221-013-0660-z10.1007/s12221-013-0660-z ↗
64. 10.1039/b804128h10.1039/b804128h ↗
65. Gerkin L. Nanoval process for spunbonds detailed. Int Fiber J. 2005;20:52–56.
66. Kim YM Ahn KR Sung YB et al. Manufacturing device and the method of preparing for the nanofibers viaelectro-blown spining process. US 7 618 579 B2 USPTO 2011.
67. Palmer L. Flash spinning. US3565979A USPTO 1968.
68. 10.1177/004051751142452410.1177/0040517511424524 ↗
69. 10.1126/science.266.5193.196110.1126/science.266.5193.1961 ↗
70. Karatas A Algan AH. KARATAŞ.Template synthesis of tubular nanostructures for loading biologically active molecules. Curr Top Med Chem. 2016;17.10.2174/1568026616666161222110859 ↗
71. 10.1021/bm025659710.1021/bm0256597 ↗
72. 10.1039/c3tb20782j10.1039/c3tb20782j ↗
73. 10.1080/15583724.2014.93585810.1080/15583724.2014.935858 ↗
74. 10.1080/00405000.2013.84268010.1080/00405000.2013.842680 ↗
75. Peno E Lipton R Kay S. Split fiber producing devices and methods for the production of microfibers and nanofibers. US8778240B2 USPTO 2012.
76. 10.1016/j.jcis.2014.03.03910.1016/j.jcis.2014.03.039 ↗
77. 10.1021/acs.macromol.5b0029210.1021/acs.macromol.5b00292 ↗
78. 10.1063/1.356709710.1063/1.3567097 ↗
79. 10.1007/978-3-319-61458-810.1007/978-3-319-61458-8 ↗
80. Bubakir M, Barhoum A, Li H, Yang W. Handbook of nanofibers (1st edtn), springer nature. 2017.
81. Willerth SM. Electrospun materials for tissue engineering and biomedical applications: research. Design and Commercialization: Woodhead Publishing; 2017.
82. 10.1002/adma.20170657010.1002/adma.201706570 ↗
83. 10.1016/j.matlet.2017.12.07910.1016/j.matlet.2017.12.079 ↗
84. 10.1016/j.actbio.2018.05.04810.1016/j.actbio.2018.05.048 ↗
85. 10.1016/j.matdes.2018.03.05310.1016/j.matdes.2018.03.053 ↗
86. 10.1002/app.3642610.1002/app.36426 ↗
87. 10.1002/pen.2313810.1002/pen.23138 ↗
88. Larrondo L St. John Manley R. Electrostatic fiber spinning from polymer melts. I. Experimental observations on fiber formation and properties. J Polym Sci Polym Phys Ed 1981; 19: 909–920.10.1002/pol.1981.180190601 ↗
89. 10.1002/biot.20060006410.1002/biot.200600064 ↗
90. Yoon Y Il Park KE Lee SJ et al. Fabrication of microfibrous and nano−/microfibrous scaffolds: melt and hybrid electrospinning and surface modification of poly(L-lactic acid) with plasticizer. Biomed Res Int 2013; 2013: 309048.10.1155/2013/309048 ↗
91. 10.1016/j.polymer.2006.08.04210.1016/j.polymer.2006.08.042 ↗
92. 10.1002/adma.20110348210.1002/adma.201103482 ↗
93. Li H, Chen H, Zhong X, et al. Interjet distance in needleless melt differential electrospinning with umbellate nozzles. J Appl Polym Sci. 2014;131:40515.10.1002/app.40515 ↗
94. 10.2298/JSC110711027L10.2298/JSC110711027L ↗
95. Hacker CJP Seide G Gries T Thomas H Moeller M. (2009) Electrospinning of polymer melt: steps toward an upscaled multi-jet process. In:proc Int confer latest advances in high tech textiles and textile-based materials: 71–76.
96. Koenig K, Daenicke J, Langensiepen F, Seide G, Schubert DW. From lab to pilot scale: melt electrospun nanofibers of polypropylene with conductive additives. J Nanomater Mol Nanotechnol. 2019;8:1.
97. 10.1002/chem.20050098410.1002/chem.200500984 ↗
98. 10.1007/s11671-010-9562-910.1007/s11671-010-9562-9 ↗
99. 10.1016/j.cis.2014.01.01910.1016/j.cis.2014.01.019 ↗
100. 10.1016/j.bioactmat.2017.09.00110.1016/j.bioactmat.2017.09.001 ↗