journal article·2011-06-03Open access

Chemical deposition of La0.7Ca0.3MnO3±δ films on ceramic substrates

Cássio Morilla-Santos, Wido Herwig Schreiner, Paulo Noronha Lisboa-Filho

Materials Research· Volume 14· Issue 2

Abstract

In this paper, it is reported the growth of La0.7Ca0.3MnO3±δ films using a chemical solution deposition method (CSD) by the spin-coating technique. Such solution was prepared through a route based on modified polymeric precursor method. Spin-coating deposition on different ceramic substrates was performed and analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The magnetic response of the prepared specimens was studied using a SQUID magnetometer. The obtained results indicated uniform deposition on SrTiO3 and LaAlO3 substrates with similar characteristics. Furthermore, significant differences were detected in the Mn3+/Mn4+ valence ratio and a corresponding diverse magnetic response was observed. The sample prepared on SrTiO3 and LaAlO3 presented a critical temperature around 270 K as expected.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics · Magnetic Properties of Alloys

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Affiliations

Universidade Estadual Paulista, Brazil

Universidade Federal do Paraná, Brazil

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