journal article·2020-11-01Open access

Effect of thermal annealing on the optical stability of amorphous Ge–Se–Te films

Jinbo Chen, Jingshuang Qin, Limeng Zhang, Yimin Chen, Xiang Shen, Jierong Gu, Tiefeng Xu

Materials Research Express· Volume 7· Issue 11

Abstract

Abstract Ge–Se–Te chalcogenide films with Ge content from 10% to 27% were prepared using thermal evaporation. The films were annealed with different times, and the changes of the linear refractive index and optical band gap of the films with different chemical compositions were investigated. It was found that, after 30 h of annealing, the Ge20Se8.5Te71.5 film exhibits the smallest change ratio in terms of linear refractive index (<0.5%), optical band gap (<1.5%), and thickness (<2.5%). Therefore, this component has the best optical stability in the Ge–Se–Te system studied in this paper. The optical band gap of Ge20Se8.5Te71.5 is about 0.8 eV, and the refractive index exceeds 3.4, which is beneficial to the applications in Te-based optical waveguide devices.
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Research context

OpenAlex topics: Phase-change materials and chalcogenides · Nonlinear Optical Materials Research · Chalcogenide Semiconductor Thin Films

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References (34)

Show source-provided references
2. Wang · 201410.1201/b15599-5 ↗
3. Optical characterization of nanocrystalline Se85Te10Pb5 and Se80Te10Pb10 chalcogenides10.1016/j.spmi.2010.03.007 ↗
4. Crystallization kinetics of Sn doped Ge20Te80−xSnx (0 ≤ x ≤ 4) chalcogenide glassy alloys10.1016/j.jallcom.2017.06.070 ↗
5. Optical properties of Ge–Se–Te wedge-shaped films by using only transmission spectra10.1016/j.jnoncrysol.2009.05.042 ↗
6. Optical study of Ge10Se90−xTex glassy semiconductors10.1016/j.tsf.2007.03.080 ↗
7. Crystallization kinetics in Se–Te glassy system10.1016/j.jnoncrysol.2011.05.002 ↗
8. Advantages of Mo4.9(Sb2Te)95.1 film with improved crystallization properties for phase change memory10.1016/j.matlet.2015.08.109 ↗
9. Photo-induced effects in Ge–As–Se films in various states10.1364/OME.385115 ↗
10. Structural relaxation and optical properties in amorphous Ge33As12Se55 films10.1016/j.jnoncrysol.2006.12.080 ↗
11. Observation of photobleaching in Ge-deficient Ge16.8Se83.2 chalcogenide thin film with prolonged irradiation10.1038/s41598-017-14796-w ↗
12. The dependence of photosensitivity on composition for thin films of GexAsySe1–x–y chalcogenide glasses10.1007/s00339-013-7585-7 ↗
13. Photo-induced changes of the short wavelength absorption edge in some Ge–As–S amorphous thin films10.1016/j.optmat.2004.07.005 ↗
14. On the properties and stability of thermally evaporated Ge–As–Se thin films10.1007/s00339-009-5293-0 ↗
15. Thermal characterization of Se–Te thin films10.1016/j.jallcom.2015.04.161 ↗
16. Optical properties and thermal stability of amorphous Ge–Sb–Se films10.1016/j.jnoncrysol.2020.119888 ↗
17. Thermal stability of magnetron sputtering Ge–Ga–S films10.1088/1674-1056/aba273 ↗
18. Far-infrared transmission and bonding arrangement in Ge10Se90−xTex semiconducting glassy alloys10.1016/j.jnoncrysol.2008.05.010 ↗
19. Electro-optical characterization of Ge–Se–Te glasses10.1016/j.jnoncrysol.2008.12.025 ↗
20. X-ray photoelectron spectra of Ge-As-Te glasses AIP10.1063/1.5040454 ↗
21. Wide-range transmitting chalcogenide films and development of micro-components for infrared integrated optics applications10.1364/OME.4.001617 ↗
22. Optical band gap tuning of Ag doped Ge2Sb2Te5 thin films10.1007/s10854-017-6921-7 ↗
23. The composition dependence of the optical band gap in Ge–Se–In thin films10.1016/j.optmat.2006.05.003 ↗
24. Physical and optical characterizations of Ge10Se90−xTex thin films in view of their spectroscopic ellipsometry data10.1016/j.jnoncrysol.2017.11.006 ↗
25. Non-hydrothermal synthesis and optical limiting properties of one-dimensional Se/C, Te/C and Se–Te/C core–shell nanostructures10.1016/j.carbon.2013.06.079 ↗
26. Thickness dependence of optical parameters for Ge–Se–Te thin films10.1016/j.matlet.2007.02.040 ↗
27. Effect of l-threonine on growth and properties of ammonium dihydrogen phosphate crystal10.1016/j.arabjc.2017.12.005 ↗
28. Effect of Sr2+ on growth and properties of ammonium dihydrogen phosphate single crystal10.1007/s10854-018-8556-8 ↗
29. Crystal growth, A.C. electrical and nonlinear optical studies of pure and dl-methionine doped ammonium dihydrogen phosphate single crystals10.1007/s10854-018-00577-2 ↗
30. Systematic z-scan measurements of the third order nonlinearity of chalcogenide glasses10.1364/OME.4.001011 ↗
31. Density and refractive index in mixtures of ionic liquids and organic solvents: correlations and predictions10.1016/j.jct.2008.01.023 ↗
32. Red Color GeSe2-based chalcohalide glasses for infrared optics10.1111/j.1551-2916.2006.01006.x ↗
33. Photo-induced phenomena in chalcogenide glasses10.1117/12.517226 ↗
34. Electronic processes in Non-Crystalline materials10.1063/1.3071145 ↗