Solution combustion synthesis of calcium aluminate nanocomposite using coffee husk extract as green fuel and its application in adsorptive amputation of anionic dyes
Source abstract
Abstract
Abstract Solution combustion synthesis of calcium aluminate (CaAl2O4) nanocomposite using coffee husk extract and its adsorption capacity for removal of Congo red (CR) and Indigo carmine (IC) are reported. Physiochemical properties of adsorbent were studied by PXRD, SEM, TEM and point of zero charge. Batch adsorption studies were conducted to study the effect of adsorbent dosage, pH, contact time, initial dye concentration and temperature on adsorption efficiency of coffee husk derived calcium aluminate nanocomposite (CHCA). Among the isotherms used, Langmuir model explained best the equilibrium data and the maximum monolayer adsorption capacity was found to be 377 and 135 mg/g for CR and IC, respectively. Mass transfer analysis indicated adsorptive removal of dyes was controlled by both external and internal diffusion. Pseudo-first-order model fitted best with experimental kinetic data and adsorption efficiency increased with an increase in the initial bulk concentration of CR and IC. Thermodynamic analysis indicated that adsorption of CR and IC on CHCA is feasible, spontaneous and exothermic in nature. The magnitude of enthalpy and heat of adsorption suggested that the adsorption is physical in nature. The present study explores the potential of coffee husk extract, an agro-based bio-waste, as a novel and eco-friendly fuel in the synthesis of CHCA and the synthesised nanocomposite as a potential adsorbent for the removal of synthetic dyes.
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Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Nanomaterials for catalytic reactions · Pigment Synthesis and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (77)
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1. Adsorption of methylene blue on low-cost adsorbents: a review10.1016/j.jhazmat.2009.12.047 ↗
2. Efficiency of various recent wastewater dye removal methods: a review10.1016/j.jece.2018.06.060 ↗
3. Dye and its removal from aqueous solution by adsorption: a review10.1016/j.cis.2014.04.002 ↗
4. Studies on batch adsorptive removal of malachite green from synthetic wastewater using acid treated coffee husk: equilibrium, kinetics and thermodynamic studies10.1016/j.microc.2018.12.067 ↗
5. Adsorption kinetics, isotherm and reusability studies for the removal of cationic dye from aqueous medium using arginine modified activated carbon10.1016/j.molliq.2019.111442 ↗
6. Adsorption of methylene blue on chemically modified pine nut shells in single and binary systems: isotherms, kinetics, and thermodynamic studies10.1080/19443994.2015.1074121 ↗
7. Decolorization of two synthetic dyes using the purified laccase of Paraconiothyrium variabile immobilized on porous silica beads10.1186/2052-336X-12-6 ↗
8. The enzymatic decolorization and detoxification of synthetic dyes by the laccase from a soil-isolated ascomycete, Paraconiothyrium variabile10.1016/j.ibiod.2013.07.006 ↗
9. Facile fabrication of porous NiCo2O4 nanosheets with high adsorption performance toward Congo red10.1016/j.jpcs.2018.10.001 ↗
10. Studies on batch adsorptive removal of malachite green from synthetic wastewater using acid treated coffee husk: equilibrium, kinetics and thermodynamic studies10.1016/j.microc.2018.12.067 ↗
11. Adsorptive performance of MOF nanocomposite for methylene blue and malachite green dyes: kinetics, isotherm and mechanism10.1016/j.jenvman.2018.05.090 ↗
12. Textile wastewater treatment by application of combined chemical coagulation, electrocoagulation, and adsorption processes10.1080/19443994.2015.1027960 ↗
13. Removal of organic pollutants from aqueous solution using agricultural wastes: a review10.1016/j.molliq.2015.10.023 ↗
14. Adsorption kinetics, isotherms, and thermodynamic studies for Hg 2+ adsorption from aqueous medium using alizarin red-S-loaded amberlite IRA-400 resin10.1080/19443994.2015.1090914 ↗
15. Adsorptive removal of toxic Methylene Blue and Acid Orange 7 dyes from aqueous medium using cobalt-zinc ferrite nanoadsorbents10.5004/dwt.2019.23751 ↗
16. Removal of colorants from wastewater: a review on sources and treatment strategies10.1016/j.jiec.2019.02.011 ↗
17. A facile one-pot hydrothermal synthesis of hydroxyapatite/biochar nanocomposites: adsorption behavior and mechanisms for the removal of copper(II) from aqueous media10.1016/j.cej.2019.03.102 ↗
18. Adsorption of dyes by nanomaterials: recent developments and adsorption mechanisms10.1016/j.seppur.2015.07.009 ↗
19. Adsorption of Pb(II) from aqueous solution using new adsorbents prepared from agricultural waste: Adsorption isotherm and kinetic studies10.1016/j.jiec.2013.09.050 ↗
20. New generation adsorbents for water treatment10.1021/cr300133d ↗
21. Removal of methyl orange from aqueous solutions through adsorption by calcium aluminate hydrates10.1016/j.jcis.2014.03.060 ↗
22. Defluoridation of water using calcium aluminate material10.1016/j.cej.2012.07.065 ↗
23. Effects of using the liquid phase method on the physicochemical, mechanical, and bioactivity properties of hydroxyapatite/calcium aluminate bioceramic nanocomposites10.1515/gps-2016-0188 ↗
24. Solution combustion synthesis of metal oxide nanomaterials for energy storage and conversion10.1039/C5NR05299H ↗
25. Review of recent studies on solution combustion synthesis of nanostructured catalysts10.1002/adem.201800047 ↗
26. Photocatalytic properties of solution combustion synthesized ZnO powders using mixture of CTAB and glycine and citric acid fuels10.1016/j.apt.2018.11.004 ↗
27. Patil · 200810.1142/9789812793157 ↗
28. Solution combustion synthesis of nanoscale materials10.1021/acs.chemrev.6b00279 ↗
29. Influence of fuel nature on dye adsorption efficiency of solution combustion derived zinc oxide nanoparticles: a comparative study10.1088/2053-1591/aafe3f ↗
30. chapter 31—an overview of the potential uses for coffee husks10.1016/B978-0-12-409517-5.00031-0 ↗
31. Influence of processing parameters on luminescent nano-structured materials synthesized by wet chemical methods
32. Adsorptive amputation of hazardous azo dye Congo red from wastewater: a critical review10.1007/s11356-016-6970-0 ↗
33. Removal of congo red dye from aqueous solutions using znfe2o4/sio2/Tragacanth gum magnetic nanocomposite as a novel adsorbent10.1016/j.surfin.2018.10.010 ↗
34. Removal of indigo carmine from aqueous solution by microwave-treated activated carbon from peanut shell10.1080/19443994.2014.967729 ↗
35. Sorption of indigo carmine by a Fe-zeolitic tuff and carbonaceous material from pyrolyzed sewage sludge10.1016/j.jhazmat.2009.05.102 ↗
36. Rice husk ash as an effective adsorbent: evaluation of adsorptive characteristics for Indigo Carmine dye10.1016/j.jenvman.2008.01.002 ↗
37. An efficient adsorption of indigo carmine dye from aqueous solution on mesoporous Mg/Fe layered double hydroxide nanoparticles prepared by controlled sol-gel route10.1016/j.chemosphere.2017.01.147 ↗
38. Characterization and application of bio-chars from liquefaction of microalgae, lignocellulosic biomass and sewage sludge10.1016/j.fuproc.2014.08.016 ↗
39. A novel agricultural waste based adsorbent for the removal of Pb(II) from aqueous solution: kinetics, equilibrium and thermodynamic studies10.1016/j.jiec.2013.05.002 ↗
40. A solid-state chemical method for synthesizing MgO nanoparticles with superior adsorption properties10.1039/C8RA09199D ↗
41. Adsorption of textile dye onto modified immobilized activated alumina10.1016/j.jaubas.2014.10.001 ↗
42. Luminescence enhancement in monoclinic CaAl2O4:Eu2+, Cr3+nanophosphor by fuel-blend combustion synthesis10.1016/j.cej.2014.12.102 ↗
43. Recent advances for dyes removal using novel adsorbents: a review10.1016/j.envpol.2019.05.072 ↗
44. Combustion synthesis of Fe3O4/Ag/C nanocomposite and application for dyes removal from multicomponent systems10.1016/j.apsusc.2019.03.161 ↗
45. Biosorption of Congo red and Indigo carmine by nonviable biomass of a new Dietzia strain isolated from the effluent of a textile industry10.1080/19443994.2012.762589 ↗
46. Hierarchical C/NiO-ZnO nanocomposite fibers with enhanced adsorption capacity for Congo red10.1016/j.jcis.2018.11.045 ↗
47. 3 Adsorption equilibrium I: general aspects and single-solute adsorption10.1515/9783110240238.41 ↗
48. Decolorisation of reactive red 120 dye by using single-walled carbon nanotubes in aqueous solutions10.1155/2013/938374 ↗
49. Sorption isotherms: a review on physical bases, modeling and measurement10.1016/j.apgeochem.2006.09.010 ↗
50. Insights into the modeling of adsorption isotherm systems10.1016/j.cej.2009.09.013 ↗
51. Relevance of isotherm models in biosorption of pollutants by agricultural byproducts10.1016/j.jece.2014.01.014 ↗
52. The constitution and fundamental properties of solids and liquids. Part I. solids10.1021/ja02268a002 ↗
53. Over the adsorption in solution
54. Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: a critical review10.1016/j.watres.2017.04.014 ↗
55. Kinetics, thermodynamics, isotherm and regeneration analysis of chitosan modified pandan adsorbent10.1016/j.jclepro.2019.05.228 ↗
56. Adsorption of rose Bengal dye from aqueous solution by amberlite Ira-938 resin: kinetics, isotherms, and thermodynamic studies10.1080/19443994.2015.1060169 ↗
57. Kinetic analysis of the adsorption of dyes from high strength wastewater on cement kiln dust10.1016/j.jece.2018.01.009 ↗
58. Nanomaterials as versatile adsorbents for heavy metal ions in water: a review10.1007/s11356-018-04093-y ↗
59. Adsorption of organic micropollutants onto biochar: a review of relevant kinetics, mechanisms and equilibrium10.1039/C8EW00938D ↗
60. Modeling in adsorption: fundamentals and applications10.1016/B978-0-12-814132-8.00005-8 ↗
61. Insight into the adsorption kinetics models for the removal of contaminants from aqueous solutions10.1016/j.jtice.2017.01.024 ↗
62. Comparative study of the batch adsorption kinetics and mass transfer in phenol-sand and phenol-clay adsorption systems10.1080/02726351.2019.1616862 ↗
63. Comparative study on removal of two basic dyes in aqueous medium by adsorption using activated carbon from Ziziphus lotus stones10.1016/j.microc.2019.02.010 ↗
64. Synthesis and application of biocompatible nontoxic nanoparticles for reclamation of Ce3+from synthetic wastewater: toxicity assessment, kinetic, isotherm and thermodynamic study10.1016/j.jre.2018.03.005 ↗
65. Isotherm and kinetic modeling on superparamagnetic nanoparticles adsorption of polysaccharide10.1016/j.jece.2017.12.063 ↗
66. H3PO4-activated carbons produced from açai stones and Brazil nut shells: removal of basic blue 26 dye from aqueous solutions by adsorption10.1007/s11356-019-04215-0 ↗
67. An insight into thermodynamics of adsorptive removal of fluoride by calcined Ca–Al–(NO3) layered double hydroxide10.1039/C5RA20538G ↗
68. Insight into adsorption thermodynamics10.5772/13474 ↗
69. Thermodynamic parameters of cadmium adsorption onto orange peel calculated from various methods: a comparison study10.1016/j.jece.2016.05.009 ↗
70. Performance of a zeolite modified with N , N -dimethyl dehydroabietylamine oxide (DAAO) for adsorption of humic acid assessed in batch and fixed bed columns10.1039/C8RA00166A ↗
71. Dye removal by eco-friendly physically cross-linked double network polymer hydrogel beads and their functionalized composites10.1016/J.JES.2018.07.006 ↗
72. An insight into the adsorption of diclofenac on different biochars: mechanisms, surface chemistry, and thermodynamics Fate of contaminants in the wastewater treatment plants view project Animal welfare view project an insight into the adsorption of diclof10.1016/j.biortech.2017.10.039 ↗
73. Removal of diclofenac sodium from aqueous solution by Isabel grape bagasse10.1016/j.cej.2012.03.062 ↗
74. Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk10.1016/j.desal.2010.07.047 ↗
75. Statistical optimization of preparing marine macroalgae derived activated carbon/iron oxide magnetic composites for sequestering acetylsalicylic acid from aqueous media using response surface methodologys10.1016/j.chemosphere.2018.10.069 ↗
76. Isotherm, kinetic and thermodynamic studies on the adsorption of 13-dehydroxybaccatin III from Taxus chinensis onto Sylopute10.1016/j.jct.2017.08.009 ↗
77. Modeling of reactive blue 19 azo dye removal from colored textile wastewater using L-arginine-functionalized Fe3O4 nanoparticles: optimization, reusability, kinetic and equilibrium studies10.1016/j.jmmm.2015.12.040 ↗