Synthesis of amorphous MgHPO4 · x(R) [R = Ethanol; Ethylene glycol] in anhydrous media
Source abstract
Abstract
New amorphous MgHPO4 · 0.80(EtOH) and MgHPO4 · x(C2H6O2) isostructural with layered MgHPO4 · 1.2H2O were synthesized using magnesium diethoxide Mg(OEt)2 and orthophosphoric acid (H3PO4) as reagents and anhydrous ethanol and ethylene glycol as solvents. The removal of intercalated ethanol or ethylene glycol occurs simultaneously with the dehydration of HPO42− ions into P2O74− ions due to a phase transition to crystalline Mg2P2O7.
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Research context
OpenAlex topics: Chemical Synthesis and Characterization · Metal-Organic Frameworks: Synthesis and Applications · Crystal Structures and Properties
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References (17)
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