New palladium phosphate complexes: K2PdP2O7 and K3.5Pd2.25(P2O7)2 synthesis, single crystal structure and conductivity
Source abstract
Abstract
Two new diphosphate complexes containing potassium and palladium, K2PdP2O7 and K3.5Pd2.25(P2O7)2, have been synthesized and characterized by single crystal X-ray diffraction. K2PdP2O7 exists with layers formed of linked PdP2O7 polyhedra, between which are found the potassium ions. K3.5Pd2.25(P2O7)2 with a Pd/P2O7 ratio of 1.125:1 crystallizes with tunnels of various sizes in which are found the potassium ions. Conductivity measurements reveal the material to be conducting.
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Research context
OpenAlex topics: Chemical Synthesis and Characterization · Inorganic Chemistry and Materials · Crystal Structures and Properties
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References (16)
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