journal article·2017-07

Pt-doped α-Fe 2 O 3 photoanodes prepared by a magnetron sputtering method for photoelectrochemical water splitting

Jiaxin Lin, Xianmin Zhang, Lianqun Zhou, Song Li, Gaowu Qin

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Abstract

Abstract Pt-doped α-Fe 2 O 3 films have been fabricated on the fluorine-doped tin oxide substrates at different substrate temperatures (300–600 °C) via a magnetron sputtering method and subsequently thermal oxidation. The structural and photoelectrochemical (PEC) properties of the films were characterized by the X-ray diffraction (XRD) technique, Energy-dispersive spectrometer (EDS), X-ray photoelectron spectroscopy (XPS) and water splitting experiment. The film fabricated at 500 °C shows the strongest diffraction peak of α-Fe 2 O 3 . EDS shows the films are composed of Fe, O and Pt, which were confirmed by the XPS measurement. The water splitting experiment indicates the doping of Pt is effective to enhance the PEC response. The film fabricated at 500 °C shows a maximum photocurrent density of 0.34 mA/cm 2 at 1.23 V versus reversible hydrogen electrode under standard illumination conditions (AM 1.5 G 100 mW/cm 2 ). The incident photon-to-electron conversion efficiency was also measured to understand the PEC water splitting for the present photoanodes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Iron oxide chemistry and applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Systematic comparison of different dopants in thin film hematite (α-Fe2O3) photoanodes for solar water splitting10.1039/C5TA07095C ↗
2. Magnetron sputtering process of carbon-doped α-Fe2O3 thin films for photoelectrochemical water splitting10.1016/j.jallcom.2015.02.166 ↗
3. Gradient doping of phosphorus in Fe2O3 nanoarray photoanodes for enhanced charge separation10.1039/C6SC03707K ↗
4. Single-crystalline, wormlike hematite photoanodes for efficient solar water splitting10.1038/srep02681 ↗
5. Pt-functionalized Fe2O3 photoanodes for solar water splitting: the role of hematite nano-organization and the platinum redox state10.1039/C5CP01636C ↗
6. c-In2O3/α-Fe2O3 heterojunction photoanodes for water oxidation10.1007/s10853-016-0085-3 ↗
7. Enhanced photocatalytic activity of hybrid Fe2O3-Pd nanoparticulate catalysts10.1039/c2sc00673a ↗
8. Photoelectrochemical water splitting at nanostructured α-Fe2O3 electrodes10.1016/j.ijhydene.2012.07.037 ↗
9. Pt-doped α-Fe2O3 thin films active for photoelectrochemical water splitting10.1021/cm800144q ↗
10. Photoelectrochemical water splitting with porous α-Fe2O3 thin films prepared from Fe/Fe-oxide nanoparticles10.1016/j.apcata.2016.06.007 ↗
11. Single crystalline hematite films for solar water splitting: Ti-doping and thickness effects10.1021/jp500290j ↗
12. Gas phase photocatalytic activity of ultrathin Pt layer coated on α-Fe2O3 films under visible light illumination10.1021/es1006737 ↗
13. Improving photoelectrochemical performance by building Fe2O3 heterostructure on TiO2 nanorod arrays10.1016/j.materresbull.2015.04.036 ↗
14. Improved photoelectrochemical responses of Si and Ti codoped α-Fe2O3 photoanode films10.1063/1.3470109 ↗
15. Controlling photoactivity in ultrathin hematite films for solar water-Splitting10.1002/adfm.200902060 ↗
16. Nanostructured hematite for photoelectrochemical generation of hydrogen10.1016/j.ijhydene.2007.07.034 ↗
17. Visible light-induced water oxidation on mesoscopic α-Fe2O3 films made by ultrasonic spray pyrolysis10.1021/jp044127c ↗
18. Translucent thin film Fe2O3 photoanodes for efficient water splitting by sunlight: nanostructure-directing effect of Si-doping10.1021/ja060292p ↗
19. Nanostructured α-Fe2O3 thin films for photoelectrochemical hydrogen generation10.1021/cm803510v ↗
20. Controlled synthesis of vertically aligned hematite on conducting substrate for photoelectrochemical cells: nanorods versus nanotubes10.1021/am200407t ↗
21. Facile hydrothermal synthesis of iron oxide nanoparticles with tunable magnetic properties10.1021/jp902953t ↗
22. New benchmark for water photooxidation by nanostructured α-Fe2O3 films10.1021/ja064380l ↗
23. Characterization and gas-sensing behavior of an iron oxide thin film prepared by atomic layer deposition10.1016/j.tsf.2007.11.011 ↗
24. Passivating surface states on water splitting hematite photoanodes with alumina overlayers10.1039/C0SC00578A ↗
25. Water splitting by tungsten oxide prepared by atomic layer deposition and decorated with an oxygen-evolving catalyst10.1002/anie.201004801 ↗
26. Photo-assisted electrodeposition of cobalt–phosphate (Co–Pi) catalyst on hematite photoanodes for solar water oxidation10.1039/c1ee01034d ↗
27. Electrodeposited zirconium-doped α-Fe2O3 thin film for photoelectrochemical water splitting10.1016/j.ijhydene.2010.11.107 ↗
28. Electrodeposited nanostructured α-Fe2O3 thin films for solar water splitting: influence of Pt doping on photoelectrochemical performance10.1016/j.matchemphys.2013.03.042 ↗
29. Sol-gel-derived iron oxide thin films on silicon: surface properties and interfacial chemistry10.1021/am900362x ↗
30. Enhancement of photoelectrochemical hydrogen production from hematite thin films by the introduction of Ti and Si10.1021/jp074556l ↗
31. Magnetron sputtering: a review of recent developments and applications10.1016/S0042-207X(99)00189-X ↗
32. Photoelectrochemical oxidation of water at transparent ferric oxide film electrodes10.1016/S0009-2614(03)00910-2 ↗
33. Solar hydrogen production with nanostructured metal oxides10.1039/b718969a ↗
34. Facile synthesis of highly photoactive alpha-Fe2O3-based films for water oxidation10.1021/nl202316j ↗
35. Solvothermal-etching process induced Ti-doped Fe2O3 thin film with low turn-on voltage for water splitting10.1021/acsami.6b06795 ↗
36. Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction10.1126/science.aaf9050 ↗
37. Synthesis of nanostructured zirconia electrodeposited films on AISI 316L stainless steel and its behaviour in corrosion resistance assessment10.1016/S0167-577X(03)00443-9 ↗
38. Electron spectroscopy of platinum-oxygen surfaces and application to electrochemical studies10.1021/ja00752a065 ↗