journal article·2017-05

Influence of anatase titania nanoparticles content on optical and structural properties of amorphous silica

Bandar Ali Al-Asbahi

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Abstract

Abstract In this work, the influence of TiO 2 NPs content on optical and structural properties of amorphous SiO 2 is investigated. Amorphous SiO 2 /TiO 2 thin films were wet-mixed and then deposited onto glass substrate by spin coating technique. The homogeneity distribution of anatase titania nanoparticles within amorphous silica matrix was evidenced by the results of X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy (FT-IR), and field emission scanning electron microscope (FE-SEM). The crystallite size of the mixed phase increased significantly upon increment of TiO 2 NPs content. The results of emission and photoluminescence excitation (PLE) confirmed the defects creation in the SiO 2 matrix. The trapped electrons and the presence of oxygen vacancies at the TiO 2 /SiO 2 interface enhanced the emission intensity of SiO 2 /TiO 2 nanocomposite thin films.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Sol-hydrothermal synthesis of inorganic-framework molecularly imprinted TiO2/SiO2 nanocomposite and its preferential photocatalytic degradation towards target contaminant10.1016/j.jhazmat.2014.05.088 ↗
2. Producing photoactive, transparent and hydrophobic SiO2-crystalline TiO2 nanocomposites at ambient conditions with application as self-cleaning coatings10.1016/j.apcatb.2014.03.042 ↗
3. Self-cleaning and depollution of fiber reinforced cement materials modified by neutral TiO2/SiO2 hydrosol photoactive coatings10.1016/j.apsusc.2013.12.171 ↗
4. Functional photocatalytically active and scratch resistant antireflective coating based on TiO2 and SiO210.1016/j.apsusc.2016.01.226 ↗
5. Silica supported TiO2 nanostructures for highly efficient photocatalytic application under visible light irradiation10.1016/j.materresbull.2015.12.040 ↗
6. Photocatalytic and self-cleaning properties of SiO2/TiO2/SiO2 nanostructured thin film10.3139/146.110976 ↗
7. Core-shell TiO2@SiO2 catalyst for transesterification of dimethyl carbonate and phenol to diphenyl carbonate10.1016/S1872-2067(14)60059-0 ↗
8. Uniform TiO2–SiO2 hollow nanospheres: synthesis, characterization and enhanced adsorption–photodegradation of azo dyes and phenol10.1016/j.apsusc.2014.03.136 ↗
9. Simple sol–gel process to obtain silica-coated anatase particles with enhanced TiO2-SiO2 interfacial area10.1016/j.jcis.2014.06.033 ↗
10. Influence of chemical conditions on the nanoporous structure of silicate aerogels10.3390/ma3010704 ↗
11. Fabrication and characterization of silica/titania nanotubes composite membrane with photocatalytic capability10.1021/es060092d ↗
12. Synthesis of large-pore mesoporous nanocrystalline TiO2 microspheres10.1016/j.matlet.2012.01.133 ↗
13. Preparation and characterization of crack-free sol–gel based SiO2–TiO2 hybrid nanoparticle film10.1007/s10971-013-3147-x ↗
14. Controlled nanostructuring of TiO2 nanoparticles: a sol–gel approach10.1007/s10971-014-3557-4 ↗
15. Preparation and hydrophilicity of TiO2 sol–gel derived nanocomposite films modified with copper loaded TiO2 nanoparticles10.1016/j.materresbull.2011.08.035 ↗
16. Modification and performances of TiO2 photocatalyst towards degradation of paraquat dichloride
17. Hydrothermal synthesis, characterization, and photocatalytic performance of silica-modified titanium dioxide nanoparticles10.1016/j.jcis.2005.02.082 ↗
18. Synthesis and characterization of copper doped tin oxide for humidity sensing applications10.1166/asl.2014.5492 ↗
19. A mechanism for enhanced hydrophilicity of silver nanoparticles modified TiO2 thin films deposited by RF magnetron sputtering10.1016/j.apsusc.2009.02.076 ↗
20. Pure and silver (2.5–40vol%) modified TiO2 thin films deposited by radio frequency magnetron sputtering at room temperature: surface topography, energy gap and photo-induced hydrophilicity10.1016/j.jallcom.2010.04.067 ↗
21. Enhanced photocatalytic activity of silver nanoparticles modified TiO2 thin films prepared by RF magnetron sputtering10.1016/j.matchemphys.2009.07.068 ↗
22. Thermo-induced hydrophilicity of nano-TiO2 thin films prepared by RF magnetron sputtering10.1016/j.jallcom.2009.06.107 ↗
23. Photocatalytic activity of TiO2 thin films deposited by RF magnetron sputtering10.1016/j.vacuum.2009.02.009 ↗
24. Optical properties of poly (9, 9-di-n-octylfluorenyl-2.7-diyl)/amorphous SiO2 nanocomposite thin films
25. Controlling the photoluminescence of ZnO:Si nano-composite films by heat-treatment10.1016/j.materresbull.2010.06.049 ↗
26. Synthesis of SiO2 nanopowders containing quartz and cristobalite phases from silica sands10.1515/msp-2015-0008 ↗
27. Cullity · 1978
28. Enhanced photocatalytic activity of hierarchical flower-like CeO2/TiO2 heterostructures10.1016/j.matlet.2016.03.136 ↗
29. TiO2–SiO2 mixed oxides: organic ligand templated controlled deposition of titania and their photocatalytic activities for hydrogen production10.1016/j.ijhydene.2012.07.047 ↗
30. Temperature dependence of the raman spectrum in anatase TiO210.1143/JPSJ.48.1661 ↗
31. Growth mechanism and photocatalytic activity of chrysanthemum-like anatase TiO2 nanostructures10.1016/j.ceramint.2016.01.011 ↗
32. Controlling the size and optical properties of ZnO nanoparticles by capping with SiO210.1016/j.materresbull.2013.09.024 ↗
33. Solvothermal synthesis of hierarchical TiO2 nanostructures with tunable morphology and enhanced photocatalytic activity10.1016/j.apsusc.2015.11.021 ↗
34. Optically active SiO2/TiO2/polyacetylene multilayered nanospheres: preparation, characterization, and application for low infrared emissivity10.1016/j.apsusc.2013.10.053 ↗
35. Enhanced photoactivity of silica-embedded titania particles prepared by sol–gel process for the decomposition of trichloroethylene10.1016/S0926-3373(99)00134-4 ↗
36. Fabrication, characterization, and photoluminescence properties of highly ordered TiO2 nanowire arrays10.1557/JMR.2001.0157 ↗
37. White phosphors from a silicate-carboxylate sol-gel precursor that lack metal activator ions10.1126/science.276.5320.1826 ↗
38. Structure and photoluminescence properties of sol–gel TiO2–SiO2 films10.1016/S0040-6090(02)00440-6 ↗
39. Optimization of UV emission intensity of ZnO nanoparticles by changing the excitation wavelength10.1016/j.matlet.2013.02.079 ↗
40. Local transport properties, morphology and microstructure of ZnO decorated SiO2 nanoparticles10.1088/0957-4484/21/41/415602 ↗
41. Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition10.1016/S0040-6090(00)00746-X ↗